Study of the effect of modification on the rheokinetics of epoxyamine composition curing using rheometry and differential scanning calorimetry
https://doi.org/10.35164/0554-2901-2022-5-6-13-15
Abstract
ITo obtain structural adhesives, a new method for modifying an epoxyamine matrix with an LPP brand adduct synthesized from oligoetherepoxide (Laproxide) in the presence of an excess of piperazine is considered. Curing kinetics of compositions has been studied by rheometry and DSC. Based on DSC data, equations that simulate curing at different stages of the process were proposed. The gelation times of the compositions have been established.
About the Authors
A. I. VYALOVRussian Federation
Korolyov, Moscow Region
A. A. SHCHERBINA
Russian Federation
Moscow
I. YU. GORBUNOVA
Russian Federation
Moscow
YU. V. OLIKHOVA
Russian Federation
Moscow
O. I. LOBAN
Russian Federation
Korolyov, Moscow Region
V. A. DYAKONOV
Russian Federation
Korolyov, Moscow Region
References
1. Клеи, клеевые связующие и клеевые препреги : [учебное пособие при подготовке бакалавров и магистров, обучающихся по направлению 22.03.01/22.04.01 "Материаловедение и технологии материалов"] / А.П. Петров, Г.В. Малышева ; под общ. ред. акад. РАН, проф. Е.Н. Каблова ; Всерос. науч.-исслед. авиац. материалов. - Москва: ВИАМ, 2017. - 471 с.
2. Загидуллин А.И., Гарипов Р.М., Ефремова А.А., Дебердеев Р.Я. //Вестник КГТУ. - 2003 - №1 - С. 313-319.
3. Гладких С.Н., Дворецкий А.Э., Вялов А.И.// Перспективные материалы. 2011. С. 358-361.
4. Gladkikh S.N., Vyalov A.I., Shestakov A.S., Shokhorova D.V.// Polymer Science. Series D. 2014. T. 7. №1. С. 23-27.
5. Arinina M.P., Il'in S.O., Malkin A.Y., Kostenko V.A., Gorbunova I.Y.// Polymer Science. Series A. 2018. Т. 60. №5. С. 683-690.
6. Bornosuz N.V., Gorbunova I.Yu., Petrakova V.V., Shutov V.V., Kireev V.V., Onuchin D.V., Sirotin I.S.// Polymers. 2021. Т. 13. №2. С. 1-16.
7. Onuchin D.V., Sirotin I.S., Pavlova G.A., Filatov S.N., Kireev V.V., Kerber M.L., Gorbunova I.Y.// Polymer Science. Series B. 2018. Т. 60. №2. С. 182-187.
8. Gorbunova I.Y., Kerber M.L., Kravchenko T.P., Bornosuz N.V., Anpilogova V.S., Piminova K.S., Tuzova S.Y.// Polymer Science. Series D. 2017. Т. 10. №1. С. 36-39.
Review
For citations:
VYALOV A.I., SHCHERBINA A.A., GORBUNOVA I.Yu., OLIKHOVA Yu.V., LOBAN O.I., DYAKONOV V.A. Study of the effect of modification on the rheokinetics of epoxyamine composition curing using rheometry and differential scanning calorimetry. Plasticheskie massy. 2022;1(5-6):13-15. (In Russ.) https://doi.org/10.35164/0554-2901-2022-5-6-13-15