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Oligourethaneepoxides based on isophorone diisocyanate as adhesion modifi ers for epoxy adhesives

https://doi.org/10.35164/0554-2901-2019-11-12-17-20

Abstract

An effect of novel oligourethaneepoxide oligomers based on isophorone diisocyanate and oligo(propylene glycol)s of different molecular masses as modifiers of epoxy resins was evaluated. Modified epoxy adhesives are characterized by reduced viscosity, enhanced adhesion to substrate, that allows to use them in the variety areas of application.

About the Authors

V. F. Matyushov
Institute of Macromolecular Chemistry of the NAS of Ukraine
Ukraine


A. L. Tolstov
Institute of Macromolecular Chemistry of the NAS of Ukraine
Ukraine


E. V. Lebedev
Institute of Macromolecular Chemistry of the NAS of Ukraine
Ukraine


References

1. Кулик Т.А., Кочергин Ю.С., Липская В.А., Гончарова О.В., Высоцкая Г.В., Веселовский Р.А., Зайцев Ю.С., Аскадский А.А. Исследование физико-механических и релаксационных свойств модифицированных каучуками эпоксидных композиций // Композиционные полимерные материалы. 1983. №19. С. 11-14.

2. Рогинская Г.Ф., Волкова В.П., Чалых А.Е., Матвеева В.В., Розенберг Б.А., Ениколопян Н.С. О механизме формирования структуры эпоксидно-каучуковых композиций // Докл. АН СССР. 1980. Т.252. №2. С. 402-405.

3. Kinloch A.J., Shaw S.J., Tod D.A., Hunston D.L. Deformation and fracture behaviour of a rubber-toughened epoxy: 1. Microstructure and fracture studies // Polymer. 1983. Vol.24. Iss.10. Р. 1341-1354.

4. Kinloch A.J., Shaw S.J., Hunston D.L. Deformation and fracture behaviour of a rubber-toughened epoxy: 2. Failure criteria // Polymer. 1983. Vol.24. Iss.10. Р. 1355-1363.

5. Hwang J.-F., Manson J.A., Hertzberg R.W., Miller G.A., Sperling L.H. Structure-property relationships in rubber-toughened epoxies // Polym. Eng. Sci. 1989. Vol.29. Iss.20. P. 14661476.

6. Hsich H.S.-Y. Morphology and properties control on rubber-epoxy alloy systems // Polym. Eng. Sci. 1990. Vol.30. Iss.9. Р. 493-510.

7. Verchere D., Pascault J.P., Sautereau H., Moschiar S.M., Riccardi C.C., Williams R.J.J. Rubber-modifi ed epoxies. II. Infl uence of the cure schedule and rubber concentration on the generated morphology // J. Appl. Polym. Sci. 1991. Vol.42. Р. 701-716.

8. Varley R.J. Toughening of epoxy resin systems using low-viscosity additives // Polym. Int. 2004. Vol.53. P. 78-84.

9. Zhang S., Cheng L., Hu J. NMR studies of water-borne polyurethanes // J. Appl. Polym. Sci. 2003. Vol.90. P. 257-260.


Review

For citations:


Matyushov V.F., Tolstov A.L., Lebedev E.V. Oligourethaneepoxides based on isophorone diisocyanate as adhesion modifi ers for epoxy adhesives. Plasticheskie massy. 2019;1(11-12):17-20. (In Russ.) https://doi.org/10.35164/0554-2901-2019-11-12-17-20

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ISSN 0554-2901 (Print)