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Vinyl-functional MQ-resins (review)

https://doi.org/10.35164/0554-2901-2019-3-4-59-65

Abstract

The review of literature and patent sources, as well as advertising materials of foreign companies, available in the public domain, on the synthesis, application and manufacturers of vinyl-functional MQ-resins. The contribution of vinyl MQ resins in the creation of organosilicon materials, widely used in various fields of modern technology, medicine and in everyday life, is shown.

About the Authors

S. V. Vinogradov
State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds
Russian Federation


A. N. Polivanov
State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds
Russian Federation


E. A. Chuprova
State Scientific Research Institute of Chemistry and Technology of Organoelement Compounds
Russian Federation


References

1. . Виноградов С.В.,Поливанов А.Н., Чупрова Е.А. Прогресс в области производства и применения MQ-смол //Химическая промышленность сегодня. 2016. №1. С.13–18.

2. Молчанов Б.В., Ким В.Д. Методы получения силоксанов, содержащих [SiO2]-звенья в основной цепи // Пластические массы. 1997. №3. С. 22–25.

3. Виноградов С.В. и др. Современное состояние технологии MQ-смол // Все материалы. Энциклопедический справочник. 2010. №10. С.35–39.

4. Robeyns C. et al. Synthesis, characterization and modification of silicone resins: An Augmented Review // Progress in organic coatings 2018. V. 125. P.287-415.

5. Pat. US 3284406. Organosiloxane encapsulating resins // Publ.1966.

6. Pat. US 4707531. Method for producing organosilicon polymers and the polymers prepared thereby // Pub. 1987.

7. Pat. US 5262558. Method of making organo-silicon polymers having mono- and tetra-functional siloxane units // Pub. 1993.

8. Pat. DE4243895(A1). Verfahren zur Herstellung von Organopolysiloxanе harz // Pub. 1994.

9. Pat. US 5861457. Organopolysiloxane resin solutions, processes for their preparation, and their use in coating compositions // Pub. 1999.

10. Pat. CN 103524741. Synthetic method of methyl vinyl MQ silicon resin // Pub. 2014.

11. Shaow Lin. Addition-Cured Silicone Adhesive Technology: Vinyl Silic one Crosslinker // J. Appl. Pol. Sci. 1994. V.54. P.2135–2145.

12. Pat. US6063889. Liquid organopolysiloxane resins, a process for their preparation, low viscosity polydiorganosiloxane compositions containing liquid organopolysiloxane resins and their use // Pub. 2000.

13. Pat. US5391673. Silicon resins and methods for their preparation // Pub. 1995.

14. Pat. US5486578. Curable silicone coatings containing silicone resins // Pub.1996.

15. Pat. CN101323667. Preparation of methyl vinyl MQ resin for LED encapsulated strengthening // Pub. 2008.

16. Pat. JP8151444. Production of organosilylated silicate // Pub. 1996.

17. Pat. US2676182. Copolymeric siloxanes and methods of preparing them // Pub. 1954.

18. Pat. US3772247. Flannigan Siloxanes // Pub. 1973.

19. Pat. US6072012. Ultra-high molecular weight, soluble siloxane resins // Pub. 2000.

20. Pat. US7951895. Process for preparing a silicone resin // Pub. 2011.

21. Pat. US3328349A. Fluorinated siloxane copolymers // Pub. 1967.

22. Lewis L. et al. Powdered MQ Resin-Platinum Complexes and Their Use as Silicone Soluble Hydrosilylation Cure Catalysts // Chem. Mater. 1997. V.9. N3. P.761–765.

23. Pat. US4611042. Resinous copolymeric siloxanes containing alkenyldimethylsiloxanes // Pub. 1986.

24. Pat. US5510430. Method of functionalizing organosiloxane condensation products // Pub. 1996.

25. Pat. US9732191. Method for capping MQ-type silicone resins // Pub. 2017.

26. Pat. RU2079516. Method for production of organosilicium resins // Pub. 1997.

27. Лезнов Н.С. и др. Полидиэтилсилоксановые жидкости. Действие карбоновых кислот на диэтилдиэтоксисилан// ЖОХ 1959, т. 29, C.1508-1514.

28. Пат. РФ 2088603. Метод получения кремнийорганических смол// Опубл. 1997.

29. Пат. РФ 2384591. Способ получения кремнийорганических смол// Опубл. 2010.

30. Pat. US3436366. Silicone potting compositions comprising mixtures of organopolysiloxanes containing vinyl groups // Pub. 1969.

31. Pat. US3445420. Acetylenic inhibited platinum catalyzed organopolysiloxane composition // Pub. 1969.

32. Pat. US3453234. Latent catalyst containing platinum and sulfoxide // Pub. 1969.

33. Pat. US3699073. Room temperature curable organopolysiloxane compositions // Pub. 1972.

34. Pat. US3914369. Process for preparing silicone rubber molds from leather masters // Pub. 1975.

35. Pat. US3957717. Organopolysiloxane compositions // Pub. 1976.

36. Pa t. US4196273. Curable organopolysiloxane compositions // Pub.1980.

37. Pat. US5994461. Liquid silicone rubber composition for application to high-voltage electrical insulators and articles // Pub.1999.

38. Pat. US3527655A. Adhesive silicone rubber // Pub.1969.

39. Pat. US4329273. Self-bonding silicone rubber compositions // Pub.1982.

40. Pat. US 5120810. Adhesive composition// Pub.1992.

41. Pat. US5164461. Addition-curable silicone adhesive compositions // Pub.1992.

42. Pat. US5475044. Addition-curable silicone adhesive compositions and bis(trialkoxysilyl)alpha-amino ester adhesion promoters//Pub.1995.

43. Pat. US4472470. Transparent membrane structures // Pub.1984.

44. Pat. US4500584. Transparent membrane structures // Pub.1985.

45. Pat. US4528314. Transparent membrane structures // Pub.1985.

46. Pat. US4618522. Organosiloxane fabric coating compositions // Pub.1986.

47. Pat. US 4746699. Curable silicone compositions // Pub. 1988.

48. Pat. US4511620 Method for prevention of bubble formation in polyorganosiloxane gels// Pub. 1985.

49. Pat. US4529789. Liquid curable polyorganosiloxane compositions // Pub. 1985.

50. Pat. US4535141. Liquid curable polyorganosiloxane compositions // Pub.1985.

51. Pat. US4701017. Touch position sensitive optical waveguides // Pub.1987.

52. Pat. US4845164. Liquid curable polyorganosiloxane compositions // Pub.1989.

53. Pat. US 4623700. Curable organopolysiloxane composition useful for coating optical fibers // Pub.1986.

54. Pat. US4689248. Silicone coated optical fibers // Pub.1987.

55. Pat. US4755577. Composition for coating optical communication glass fiber // Pub.1988.

56. Pat. US4882398. Optically clear reinforced organosiloxane compositions // Pub.1989.

57. Pat. JPS54081363. Manufacture of silicone contact lens // Pub.1979.

58. Pat. US5077335. Optically clear silicone compositions // Pub. 1991.

59. Pat. US5623029 Reinforced compositions and lens bodies made from same//Publ.1997.

60. Pat. US5403885. Transparent material for dental applications // Pub.1995.

61. Pat. US5830951. Polyvinylsiloxane impression material // Pub.1998.

62. Pat. US6313190. Addition cross-linking, two-component silicone material with high shore hardness and high modulus of elasticity // Pub. 2001.

63. Pat. US7951891. Silicone resin composition for die bonding // Pub. 2011.

64. Pat. CN104232009. Preparation method and application of vinyl MQ resin modified organosilicone packaging adhesive // Pub. 2016.

65. Pat. US8691910. Curable silicone composition // Pub. 2014.

66. Pat. US8859693. Curable silicone composition that provides a highly transparent cured silicone material // Pub. 2014.

67. Pat. US4329274. Heat curable organopolysiloxane compositions // Pub.1982.

68. Pat. US4340709. Addition curing silicone compositions // Pub.1982.

69. Pat. US4382057. Silicone rubber compositions for liquid injection molding machines // Pub.1983.

70. Pat. US4427801. Extrudable silicone elastomer compositions // Pub.1984.

71. Pat. US6004679. Laminates containing addition-curable silicone adhesive compositions // Pub.1999.

72. Pat. US4041010. Solvent resistant room temperature vulcanizable silicone rubber compositions // Pub.1985.

73. Pat. US4537829. Curable silicone compositions comprising resins // Pub.1985.

74. Pat. US4599374. Solvent resistant vulcanizable silicone rubber compositions made with fluorosilicone hydride cross linking agents // Pub.1986.

75. Pat. US5756598. Resin-containing organosiloxane compositions curable to silicone elastomers having low weep // Pub.1998.

76. Pat. US6063889. Liquid organopolysiloxane resins, a process for their preparation, low viscosity polydiorganosiloxane compositions containing liquid organopolysiloxane resins and their use // Pub. 2000.

77. Pat. US6884314. Conducive, silicone-based compositions with improved initial adhesion reduced microvoiding // Pub. 2005.

78. Pat. US5877256. Liquid silicone rubber coating composition for application to air bags // Pub.1999.

79. Pat. US8828551. Silicone composition and process that is useful for improving the tear strength and the combing strength of an inflatable bag for protecting an occupant of a vehicle // Pub. 2014.

80. Pat. US9242616. Coating compositions and textile fabrics coated therewith // Pub. 2016.

81. Pat. US4539357. Peroxide curing polysiloxane compositions having a high tear strength // Pub.1985.

82. Pat. US 5122562. Heat curable silicone rubber compositions// Pub.1992.

83. Pat. CA2087751. Heat curable silicone rubber compositions employing vinyl MQ resin and a single vinyl chain stopped polymer // Pub.1993.

84. Pat. CA2087777. Heat cured elastomer compositions based on a vinyl functional resin, a single vinyl chain-stopped polymer, and vinyl-on-chain polymers // Pub.1993.

85. Pat. US8293810. Rapid prototyping resin compositions // Pub. 2012.

86. Pat. US3527659. Dimethylpolysiloxanes and copolymers containing SiO2 units as release agent // Pub.1970.

87. Pat. US4123604. Process for coating a substrate and an improved coating therefore // Pub.1978.

88. Pat. US4293671. Organopolysiloxane composition for preparing peelable film // Pub.1981.

89. Pat. GB2045788. Method for coating a substrate using a curable silicone release composition // Pub.1980.

90. Pat. US6274692. Cross-linkable compounds, optionally containing MQ silicone resins // Pub. 2001.

91. Pat. EP0108208. Solventless silicone controlled release compositions // Pub.1984.

92. Pat. US5468816. Silicone release compositions // Pub.1995.

93. Pat. US5861457. Organopolysiloxane resin solutions, processes for their preparation, and their use in coating compositions // Pub.1999.

94. Pat. US9758701. Release modifier composition // Pub. 2017.

95. Pat. US5386007. Siloxane copolymers containing alkenyl groups, their preparation and their use // Pub.1995.

96. Pat. US5446087. Curable release compositions comprising novel silicone adhesion modifier // Pub.1995.

97. Pat. US5696211. Silicone release coating compositions // Pub.1997.

98. Pat. US5545831. Silicone compositions for the formation of cured release coatings // Pub.1996.

99. Pat. US4244912. Molding process using curable silicone release compositions // Pub.1981.

100. Pat.US3317455. Thermal insulation and ablation material // Pub.1967.

101. Pat.US3475262. Spacecraft heat shield construction and method of making same// Pub.1969.

102. Pat. US4269753. Siloxane compositions which can be ceramified at high temperatures // Pub.1981.

103. Pat. US4269757. Siloxane compositions which form ceramics at high temperatures // Pub.1981.

104. Pat. US4418157. Low density silicone foam compositions and method for making // Pub.1983.

105. Pat.US6121368. Silicone composition and silicone pressure sensitive adhesive formed therefrom//Pub.2000.

106. Pat. US4431472. Method for improving the adhesion of organopolysiloxane elastomers // Pub.1984.

107. Pat. US4533687. Flame-retardant rubber composition // Pub.1985.

108. Pat. US48616701. Marine foulant release coating // Pub.1989.

109. Pat. US4889576. Method for joining silicone-coated fabrics // Pub.1989.

110. Pat. US5696209. Dual-cure flowable adhesive // Pub.1997.

111. Pat. US6207722. Foam control compositions having resin-fillers // Pub. 2001.

112. Pat. US6365670 Organopolysiloxane gels for use in cosmetics// Pub. 2002

113. Pat. US6881416. Alkyl group-substituted organopolysiloxane gels // Pub. 2005.

114. Pat. CN101386706. Solvent-free flame-retardant glass fiber sili cone resin // Pub. 2009.

115. siltech.com

116. millikenchemical.com/sivance/

117. gelest.com/wp-content/uploads/Reactive-SIlicones-2016.pdf

118. corporate.evonik.com/en

119. nusil.com/about

120. brb-international.com/about

121. iotachem.com/listproduct.php?id=2

122. plastics.ulprospector.com/manufacturers

123. en.cgfse.com

124. greatchinasilicon.com/about_en.html

125. rljchem.com/template/introduce_en.html

126. chinarunhe.com/product_detail_en/id/12.html

127. runhesilicone.com/silicone-fluid/silicone-resin/

128. xibohg.com/en/index.asp

129. btlchemical.com/About-17.html

130. sisib.com/profile/products.html

131. kingfirstchem.com/products_detail/productId=88.html


Review

For citations:


Vinogradov S.V., Polivanov A.N., Chuprova E.A. Vinyl-functional MQ-resins (review). Plasticheskie massy. 2019;(3-4):59-65. (In Russ.) https://doi.org/10.35164/0554-2901-2019-3-4-59-65

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