Preview

Plasticheskie massy

Advanced search

Cyclopropanation of polyvinyl alcohol

https://doi.org/10.35164/0554-2901-2023-3-4-28-29

Abstract

The esterification reaction of polyvinyl alcohol with para-aminophenylcyclopropane carboxylic acyl chloride has been studied in order to obtain a diversified polymer containing fragments of polyvinyl alcohol and groups, amino and cyclopropane rings, as well as other fragments in the side links of the macromolecule. As a result of the study, a new polymer was synthesized and its composition and structure were determined on the basis of IR and NMR spectroscopy data. The properties of the synthesized polymer have been studied and it has been established that the modified polymer has high antimicrobial properties, which makes it possible to use it as an antimicrobial substance in medicine.

About the Authors

K. G. Guliyev
Institute of Polymer Materials of Azerbaijan National Academy of Sciences
Azerbaijan

Sumgait



V. E. Vakhabova
Institute of Polymer Materials of Azerbaijan National Academy of Sciences
Azerbaijan

Sumgait



References

1. A. Munoz-Banilla, M. Fernandez-Garcia. Polymeric materials with antimicrobial activity // Progress Polymerr. Sci. 2012 V.37. p. 281-339.

2. Донцова Э.П., Жарненкова О.А., Снежко А.Г., Узденский В.Б. Полимерные материалы с антимикробными свойствами // Пластик, 2014, Т. 131, №1-2, с. 30-35.

3. Ивашев М.Н., Круглая А.А., Савенко И.А. Усманский Ю.В., Сергиенко А.В., Лысенко Т.А., Куянцева А.М., Арльт А.В., Зацепина Е.Е., Ефремова М.П., Шемонаева М.В., Масликова Г.В., Сампиева К.Т., Струговщик Ю.С., Врубель М.Е., Алиева М.У. Биологическая активность соединений, полученных синтетическим путем, Фундаментальные исследования №7, 2012, с. 441-444.

4. Tatsuo Tashiroa, Antibacterial and Bacterium Adsorbing Macromolecules, Macromol. Mater. Eng. 2001, 286, p. 63–87.

5. El-Refaie Kenawy, S. D. Worley, and Roy Broughton The Chemistry and Applications of Antimicrobial Polymers: A State-of-the-Art Review, Biomacromolecules, Vol. 8, No. 5, 2007 p. 1359-1384

6. Salaun J. Cyclopropane derivatives and their diverse biological activities. Topics in current chemistry: ring compounds in organic synthesis VI, 2000, pp. 1-67.

7. Бардасов И.Н., Голубев Р.В., Алексеева А.Ю. и др. Синтез и биологическая активность оксиранов и циклопропанов на основе арилиденпроизводных димера малононитрила. Вестник Казанского технологического университета, 2010, №9, с. 116-119.

8. Wei Ke, Na-Bo Sun,d Hong-Ke Wu. Synthesis, Crystal Structure and Biological Activity of 4-Cyclopropyl-3-[(3-fl uorobenzyl)thio]5-methyl-4H-1,2,4-triazole Monohydrate. Asian J. Chem, 2013, Vol. 25, N. 15, pp. 8723-8726.

9. A. Carpov, D. Dragan, Angew, Macromolec. Chemie, 24, 101, 1972.

10. F.W. Harris, L.K. Post, Polymer Preprints, 16, 622, 1975.

11. Коршак В.В., Штильман М.И., Ярошенко И.В., Овчаров К.Е., Авт. Свид. 426495, 1974.

12. Коршак В.В., Штильман М.И., Ярошенко И.В. Высокомолекулярные соединения, В19, 234, 1977.

13. Коршак В.В., Штильман М.И., Ярошенко И.В. Высокомолекулярные соединения, В18, 856, 1976.

14. A. Carpov, S. Maxim, M.Dima, Rev. Roumania chemie, 21, 1097, 1976.

15. B.М. Савинов, Л.Б. Соколов. Высокомолекулярные соединения 7, 2156, 1965.

16. M.Tsuda, Macromolec.chem. 72, 174. 1964.

17. Шермергорн И.М., Камардин Ю.Б., Магдеев И.М. Высокомолек. Соед., Б9 419, 1967.


Review

For citations:


Guliyev K.G., Vakhabova V.E. Cyclopropanation of polyvinyl alcohol. Plasticheskie massy. 2023;(3-4):28-29. (In Russ.) https://doi.org/10.35164/0554-2901-2023-3-4-28-29

Views: 147


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0554-2901 (Print)