Synthesis and study of properties of polyazomethines based on carbamide and aromatic dialdehydes
https://doi.org/10.35164/0554-2901-2022-5-6-32-35
Abstract
New polyazomethines were synthesized by low-temperature polycondensation of urea and aromatic dialdehydes. The optimal conditions for the process of obtaining polyazomethines have been determined. The structure of the obtained polyazomethines was determined by IR spectroscopy and elemental analysis methods. The synthesized polyazomethines are partially crystalline, highly soluble and fusible materials. It was established that the synthesized polyazomethines have an increased thermal stability, which depends on the structure of the initial aromatic dialdehyde. It was found that polyazomethine based on carbamide and 4,4’-diform yldiphenoxyterephthalate melts, exhibiting liquid crystalline properties. It was shown that the obtained polyazomethines are fiber and film-forming materials.
About the Authors
T. A. BORUKAEV
Kabardino-Balkar state University named H. M. Berbekov
Russian Federation
Russian Federation
Nalchik
L. I. KITIEVA
Ingush state University
Russian Federation
Russian Federation
Magas
A. KH. MALAMATOV
Kabardino-Balkar state University named H. M. Berbekov
Russian Federation
Russian Federation
Nalchik
References
1. Овденко В.Н., Сыромятников В.Г., Колендо А.Ю. Полиазометины. Синтез, свойства и применение (обзор) // Полимерные материалы и технологии. 2017. Т.3. №1. С. 6-31.
2. Issam A.M., Ismail J. Improvement of Thermal Stability of New Heteroaromatic Poly(azomethine urethane)s // J. Appl. Polym. Sci. – 2006. Vol.100. P. 1198-1204.
3. Hindson J.C., Ulgut B., Friend R.H., Greenham N.C., Norder B., Kotlewskic A., Dingemans T.J. All-aromatic liquid crystal triphenylamine-based poly(azomethine)s as hole transport materials for opto-electronic applications // J. Mater. Chem. 2010. Vol. 20. P. 937-944.
4. Михайлин Ю.А. Жидкокристаллические полимеры // Полимерные материалы. 2006. №2. С. 24-30.
5. Ozeryanskii V.A., Pozharskii A.F., Schilf W., Kamieński B., Sawka-Dobrowolska W., Sobczyk L., Grech E. Novel Polyfunctional Tautomeric Systems Containing Salicylideneamino and Proton Sponge Moieties // Eur. J. Org. Chem. 2006. P. 782-790.
6. Ravikumar L., Prasad M.B., Vasanthi B.J, Gopalakrishnan K., Rajeshkumar J., Sengodan V. Synthesis, characterization and electrical conductivity of new poly (azomethine ester)s from hydroxy acids // Mater. Chem. Phys. 2009. Vol.115. P. 632-636.
7. Александрова Е.Л. Светочувствительные полимерные полупроводники (обзор) // Физика и техника полупроводников. 2004. Т. 38. Вып. 10. С. 1153-1194.
8. Catanescu O., Grigoras M., Colotin G., Dobreanu A., Hurduc N., Simionescu C.I. Synthesis and characterization of some aliphaticaromatic poly(Schiff base)s // Eur. Polymer J. 2001. Vol. 37. P. 2213-2216.
9. Левин О.В. Полимерные комплексы основания Шиффа с металлами селенного типа // Вестник технологического университета. 2016. Т.19. №22. С. 5-15.
10. M.A. Hussein, M.A. Abdel-Rahman, A.M. Asiri, K.A. Alamry, K.I. Aly. Review on: liquid crystalline polyaxomethines polymers. Basics, syntheses and characterization // Designed Monomers and Polym. 2012. Vol.15. Р. 431-435.
11. Zalova T.V., Borukaev T.A. Polyazomethine-esters based on new aromatic dialdehydes // J. of the Balkan Tribological Association. 2010. Vol.16. №2. Р. 279-283.
12. Tsai Fu-Chuan, Chang Chao-Ching, Liu Cheng-Liang, Chen WenChang, Jenekhe Samson A. New thiophenelinked conjugated poly(azomethine)s: Theoretical electronic structure, synthesis and properties // Macromolecules. 2005. Vol. 38. №5. P. 1958-1966.
13. Бюллер К.-У. Тепло- и термостойкие полимеры / Пер. с нем. Н.В. Афанасьева, Г.М. Цейтлина. – М.: Химия, 1984. – 1056 с.
14. Бартенев Г.М., Френкель Г.М. Физика полимеров / Под ред. д-ра физ.-мат. наук А.М. Ельяшевича. – Л.: Химия, 1990. – 432 с.
15. Шибаев В.П. Жидкокристаллические полимерные системы – от прошлого к настоящему // Высокомолек. соединения. Серия А. 2014. Т. 56. №6. С. 727-762.
Review
For citations:
BORUKAEV T.A., KITIEVA L.I., MALAMATOV A.Kh. Synthesis and study of properties of polyazomethines based on carbamide and aromatic dialdehydes. Plasticheskie massy. 2022;1(5-6):32-35. (In Russ.) https://doi.org/10.35164/0554-2901-2022-5-6-32-35
Views:
257
Email this article 
