Study of polyethylene terephthalate glycolysis with a mixture of bis(2-hydroxyethyl) terephthalate and its oligomers
https://doi.org/10.35164/0554-2901-2021-3-4-50-52
Abstract
In this work, glycolysis of post-consumer polyethylene terephthalate with simultaneous dissolution and decomposition with a mixture of bis(2-hydroxyethyl) terephthalate and its oligomers is studied. High efficiency of this process was shown. For the glycolysis agent containing 75 wt% bis(2-hydroxyethyl) terephthalate and 25 wt% dimer and oligomers, the optimal molar ratio of the glycolysis agent units to the polyethylene terephthalate units is 5:1. On the basis of the process, a productive and cost-effective technology can be developed for the chemical destruction of post-consumer polyethylene terephthalate. A formula for calculating the bis(2-hydroxyethyl) terephthalate conversion taking into account the presence of oligomers in it is proposed.
About the Authors
K. A. KirshanovRussian Federation
Moscow
R. V. Toms
Russian Federation
Moscow
References
1. Киршанов К.А. Получение сложных олигоэфиров направленной гликолитической деструкцией отходов полиэтилентерефталата / К.А. Киршанов, А.Ю. Гервальд, Р.В. Томс // Пластические массы. – 2020. – № 11-12. – С. 51-53.
2. Stoski A. Oligomer production through glycolysis of poly(ethylene terephthalate): effects of temperature and water content on reaction extent / A. Stoski, M.F. Viante, C.S. Nunes, E.C. Muniz, M.L. Felsner, C.A.P. Almedia // Polymer International. – 2016. – V. 65. – I. 9.
3. Bo Liu. Ultrafast homogeneous glycolysis of waste polyethylene terephthalate via a dissolution-degradation strategy / Bo Liu, Xingmei Lu, Zhaoyang Ju, Peng Sun, Jiayu Xin, Xiaoqian Yao, Qing Zhou, Suojiang Zhang // Industrial & engineering chemistry research. – 2018. – V. 57. – I. 48. – P. 16239-16245.
4. Пат. US 5051528 A США, МПК C07C 67/60; CO7C 27/26. Recovery process for ethylene glycol and dimethylterephthalate / A.A. Naujokas, K.M. Ryan. – № 521070; заявлено 24.04.1991; опубликовано 24.09.1991. – 4 с.
5. Пат. WO 2016/096768 A1 всемирный, МПК C08J3/24; C08J 11/16; C07C 69/82; C07C 67/03. Method for glycolysis of polyethylene terephthalate in two reaction steps / V. Coupard, F. Bazer-Bachi, W. Weiss, F. Hugues. – № PCT/EP2015/079658; заявлено 14.12.2015; опубликовано 23.06.2016. – 21 с.
6. El Mejjatti A. Chemical recycling of poly(ethylene terephthalate). Application to the synthesis of multiblock copolyesters / A. El Mejjatti, T. Harit, A. Riahi, R. Khiari, I. Bouabdallah, F. Malek // eXPRESS Polymer Letters. – 2014. – V. 8. – № 8. – P. 544-553.
7. Lopez-Fonseca R. Chemical recycling of post-consumer PET wastes by glycolysis in the presence of metal salts / R. Lopez-Fonseca, Duque-Ingunza, B. de Rivas, S. Arnaiz, J.I. Gutierrez-Ortiz // Polymer Degradation and Stability. – 2010. – V. 95. – P. 1022-1028.
8. Goh H.W. Time, temperature and amount of distilled water effects on the purity and yield of bis(2-hydroxyethyl) terephthalate purification system / H.W. Goh, A. Salmiaton, N. Abdullah, A. Idris // Bulletin of Chemical Reaction Engineering & Catalysis. – 2015. – V. 10. – №2. – P. 143-154.
9. Viana M.E. Chemical recycling of PET by catalyzed glycolysis: Kinetics of the heterogeneous reaction / M.E. Viana, A. Riul, G.M. Carvalho, A.F. Rubira, E.C. Muniz // Chemical Engineering Journal. – 2011. – V. 173. – P. 210-219.
10. Обзор рынка вторичного полиэтилентерефталата (ПЭТ) в России. Объединение независимых экспертов в области минеральных ресурсов, металлургии и химической промышленности. Исследовательская группа ИНФОМАЙН. Москва. 2015 год [Электронный ресурс]. URL: http://www.infomine.ru. Дата обращения: 21.08.2020.
11. Sce F. Comparing Conventional and Microwave-Assisted Heating in PET Degradation Mediated by Imidazolium-Based Halometallate Complexes / F. Sce, I. Cano, C. Martin, G. Beobide, O. Castilloc, de Pedro // New Journal if Chemistry. – 2019. – I. 43. – P. 3476-3485.
Review
For citations:
Kirshanov K.A., Toms R.V. Study of polyethylene terephthalate glycolysis with a mixture of bis(2-hydroxyethyl) terephthalate and its oligomers. Plasticheskie massy. 2021;(3-4):50-52. (In Russ.) https://doi.org/10.35164/0554-2901-2021-3-4-50-52