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Study of polyethylene terephthalate glycolysis with a mixture of bis(2-hydroxyethyl) terephthalate and its oligomers

https://doi.org/10.35164/0554-2901-2021-3-4-50-52

Abstract

In this work, glycolysis of post-consumer polyethylene terephthalate with simultaneous dissolution and decomposition with a mixture of bis(2-hydroxyethyl) terephthalate and its oligomers is studied. High efficiency of this process was shown. For the glycolysis agent containing 75 wt% bis(2-hydroxyethyl) terephthalate and 25 wt% dimer and oligomers, the optimal molar ratio of the glycolysis agent units to the polyethylene terephthalate units is 5:1. On the basis of the process, a productive and cost-effective technology can be developed for the chemical destruction of post-consumer polyethylene terephthalate. A formula for calculating the bis(2-hydroxyethyl) terephthalate conversion taking into account the presence of oligomers in it is proposed.

About the Authors

K. A. Kirshanov
MIREA - Russian Technological University
Russian Federation

Moscow



R. V. Toms
MIREA - Russian Technological University
Russian Federation

Moscow



References

1. Киршанов К.А. Получение сложных олигоэфиров направленной гликолитической деструкцией отходов полиэтилентерефталата / К.А. Киршанов, А.Ю. Гервальд, Р.В. Томс // Пластические массы. – 2020. – № 11-12. – С. 51-53.

2. Stoski A. Oligomer production through glycolysis of poly(ethylene terephthalate): effects of temperature and water content on reaction extent / A. Stoski, M.F. Viante, C.S. Nunes, E.C. Muniz, M.L. Felsner, C.A.P. Almedia // Polymer International. – 2016. – V. 65. – I. 9.

3. Bo Liu. Ultrafast homogeneous glycolysis of waste polyethylene terephthalate via a dissolution-degradation strategy / Bo Liu, Xingmei Lu, Zhaoyang Ju, Peng Sun, Jiayu Xin, Xiaoqian Yao, Qing Zhou, Suojiang Zhang // Industrial & engineering chemistry research. – 2018. – V. 57. – I. 48. – P. 16239-16245.

4. Пат. US 5051528 A США, МПК C07C 67/60; CO7C 27/26. Recovery process for ethylene glycol and dimethylterephthalate / A.A. Naujokas, K.M. Ryan. – № 521070; заявлено 24.04.1991; опубликовано 24.09.1991. – 4 с.

5. Пат. WO 2016/096768 A1 всемирный, МПК C08J3/24; C08J 11/16; C07C 69/82; C07C 67/03. Method for glycolysis of polyethylene terephthalate in two reaction steps / V. Coupard, F. Bazer-Bachi, W. Weiss, F. Hugues. – № PCT/EP2015/079658; заявлено 14.12.2015; опубликовано 23.06.2016. – 21 с.

6. El Mejjatti A. Chemical recycling of poly(ethylene terephthalate). Application to the synthesis of multiblock copolyesters / A. El Mejjatti, T. Harit, A. Riahi, R. Khiari, I. Bouabdallah, F. Malek // eXPRESS Polymer Letters. – 2014. – V. 8. – № 8. – P. 544-553.

7. Lopez-Fonseca R. Chemical recycling of post-consumer PET wastes by glycolysis in the presence of metal salts / R. Lopez-Fonseca, Duque-Ingunza, B. de Rivas, S. Arnaiz, J.I. Gutierrez-Ortiz // Polymer Degradation and Stability. – 2010. – V. 95. – P. 1022-1028.

8. Goh H.W. Time, temperature and amount of distilled water effects on the purity and yield of bis(2-hydroxyethyl) terephthalate purification system / H.W. Goh, A. Salmiaton, N. Abdullah, A. Idris // Bulletin of Chemical Reaction Engineering & Catalysis. – 2015. – V. 10. – №2. – P. 143-154.

9. Viana M.E. Chemical recycling of PET by catalyzed glycolysis: Kinetics of the heterogeneous reaction / M.E. Viana, A. Riul, G.M. Carvalho, A.F. Rubira, E.C. Muniz // Chemical Engineering Journal. – 2011. – V. 173. – P. 210-219.

10. Обзор рынка вторичного полиэтилентерефталата (ПЭТ) в России. Объединение независимых экспертов в области минеральных ресурсов, металлургии и химической промышленности. Исследовательская группа ИНФОМАЙН. Москва. 2015 год [Электронный ресурс]. URL: http://www.infomine.ru. Дата обращения: 21.08.2020.

11. Sce F. Comparing Conventional and Microwave-Assisted Heating in PET Degradation Mediated by Imidazolium-Based Halometallate Complexes / F. Sce, I. Cano, C. Martin, G. Beobide, O. Castilloc, de Pedro // New Journal if Chemistry. – 2019. – I. 43. – P. 3476-3485.


Review

For citations:


Kirshanov K.A., Toms R.V. Study of polyethylene terephthalate glycolysis with a mixture of bis(2-hydroxyethyl) terephthalate and its oligomers. Plasticheskie massy. 2021;(3-4):50-52. (In Russ.) https://doi.org/10.35164/0554-2901-2021-3-4-50-52

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