Kinetic aspects of the concentration of solid nanoparticles at the interface in a polymers bland
Abstract
The effect of the parameters of the mixing process on the regularity of concentration of carbon black particles at the interface between polymer components in mixtures of polyethylene with polystyrene is studied. Concentration of the filler at the interface is facilitated by a decrease in shear stress, viscosity of polymers, particle size of the filler.
About the Authors
A. E. Zaikin
Казанский национальный исследовательский технологический университет
Russian Federation
Russian Federation
A. R. Achmetov
Казанский национальный исследовательский технологический университет
Russian Federation
Russian Federation
T. M. Tsentovskiy
Казанский национальный исследовательский технологический университет
Russian Federation
Russian Federation
References
1. Chen J., Cui X., Zhu Y., Jiang W., Sui K. Design of superior conductive polymer composite with precisely controlling carbon nanotubes at the interface of a co-continuous polymer blend via a balance of p-p interactions and dipole-dipole interactions // Carbon 2017. V.114. P.441-448.
2. Bai L., He S., Fruehwirth J. W., Stein A., Macoskoa C.W., Cheng X. Localizing graphene at the interface of cocontinuous polymer blends: Morphology, rheology, and conductivity of cocontinuous conductive polymer composites// J. Rheology 2017. V.61, №4. P.575-587.
3. Zhang Q., Wang J., Yu J., Guo Z.-X. Improved electrical conductivity of TPU/carbon black composites by addition of COPA and selective localization of carbon black at the interface of sea-island structured polymer blends //Soft Matter, 2017. V.13. №18. P.3431-3439.
4. Заикин А.Е. Павлий В.Г., Кузнецов Е.В. О влиянии техуглерода на изменение взаимодействия в бинарной смеси полимеров // Высокомолек. соед. А. 1987. Т.29. №3. С.447-450.
5. Sumita M., Sakata K., Asai S., Miyasaka K., Nakagawa H. Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black // Polymer Bulletin, 1991. V.25. №2. P.265-271.
6. Gubbels F., Jerome R., Teyssie Ph., Vanlathen E., Deltour R., Calderone A., Parente V., Bredas J.L. Selective Localization of Carbon Black in Immiscible Polymer Blends // Macromolecules, 1994. V.27. №7. P.1972-1974.
7. Zaikin A. E., Mindubaev R. Y., Arkhireev V. P. A study of the localization of carbon black particles at the interfaces in heterogeneous polymer blends // Colloid journal Russian Academy Sciences, 1999. V.61. №4. P.459-502.
8. Elias L., Fennouillot F., Majeste J.-C., Martin G., Cassagnau P. Migration of Nanosilica Particles in Polymer Blends // J. Polymer Sci.: Part B: Polymer Physics, 2008. V.46. №18. P.1976-1983.
9. Ray S. S., Bousmina M. Morphology and Properties of Organoclay Modified Polycarbonate/Poly(methyl methacrylate) Blend //Polymer Eng. Sci. 2006. V.46. №8. P.1121-1129.
10. Zaikin A. E., Bobrov G. B. Compatibilization of Blends of Incompatible Polymers via Filling //Polymer Science, Ser. A. 2012. V.54. №8. P.651657.
11. Vo L.T., Giannelis E.P. Compatibilizing Poly(vinylidene fluoride)/Nylon-6 Blends with Nanoclay //Macromolecules, 2007. V. 40. № 23. P. 8271-8276.
12. Mallick S., Kar P., Khatua B. B. Morphology and Properties of Nylon 6 and High Density Polyethylene Blends in Presence of Nanoclay and PE-g-MA //J. Appl. Polym. Sci. 2012. V.123. №3. P.1801-1811.
13. Adamson A.W. Physical chemistry of surfaces. New York: Wiley, 1976.
14. Colloidal particles at liquid interfaces / Ed. by B.P. Binks, T.S. Horozov. Cambridge: Cambridge University Press. 2006. 503p.
15. Elias L., Fenouillot F., Majeste J.C., Alcouffe P., Cassagnau P. Immiscible polymer blends stabilized with nano-silica particles // Polymer, 2008. V. 49. № 20. P.4378-4385.
16. Elias L., Fenouillot F., Majeste J.C., Cassagnau Ph. Morphology and rheology of immiscible polymer blends filled with silica nanoparticles // Polymer, 2007. V.48. №20. P.6029-6040.
17. Zaikin A. E., Zharinova E. A., Bikmullin R. S. Specifics of Localization of Carbon Black at the Interface between Polymeric Phases //Polymer Science, Ser. A. 2007. V.49. №3. P.328.
18. Zaikin A. E., Karimov R. R., Arkhireev V. P. The study of the redistribution of carbon black particles from the bulk to the interface in heterogeneous polymer blends// Colloid Journal, 2001. V.63. №1. P.53-59.
19. Zaikin A. E., Mindubaev P. Yu., Arkhireev V. P. Electric conductivity of heterogeneous polymer blendsfilled with carbon black // Polymer Science, Ser. B. 1999. V.41. №1-2. P.15-19.
20. Fenouillot F., Cassagnau P., Majeste J.-C. Uneven distribution of nanoparticles in immiscible fluids // Polymer, 2009. V.50. №6. P.1333-1350.
21. Gubbels F., Jerome R., Vanlathem E., Deltour R., Blacher S., Brouers F. Kinetic and Thermodynamic Control of the Selective Localization of Carbon Black at the Interface of Immiscible Polymer Blends // Chem. Mater. 1998. V.10. №5. P.1227-1235.
22. Feng J., Chan C-M., LI J.-X. Method To Control the Dispersion of Carbon Black in an Immiscible Polymer Blend // Polymer Eng. Sci. 2003. V.43. №5. P.1058-1063.
23. Zaikin A.E., Bikmullin R.S., Gorbunova I.A. Characterization of the Adhesion Interaction of Polymers with the Surface of Filler Nanoparticles // Russian J. Appl. Chem. 2007. V.80. №6. P.965-970.
24. Wu S.J. Calculation of interfacial tension in polymer systems // J. Polymer Sci. Part.C. 1971. V.34. №1. P.19-30.
Review
For citations:
Zaikin A.E., Achmetov A.R., Tsentovskiy T.M. Kinetic aspects of the concentration of solid nanoparticles at the interface in a polymers bland. Plasticheskie massy. 2019;(1-2):13-17. (In Russ.)
Views:
339
Email this article 
