Synthesis and properties of polymeric optical multisensors for gas analysis. I. Immobilization of brilliant green on polymethacrylic acid

Polymethacrylic acid loaded with the brilliant green dye has been synthesized and described by the methods of IR and UV spectroscopy. A film based on such polymer showed a satisfactory performance in the chemisorption of ammonia, sulfur dioxide, hydrogen sulfide and is a promising optical multisensor for gas analysis.

polymethacrylic acid, brilliant green, immobilization, IR spectroscopy, UV spectroscopy, polymeric optical multisensors, chemisorption, ammonia, hydrogen sulfide, sulfur dioxide

1. Каттралл Р.В. Химические сенсоры. М. Научный мир. 2000, 144 с.

2. Grundler P. Chemical sensors: an introduction for scientists and engineers. Berlin. London. Springer, 2007.- 273 p.

3. Сысоев, В.В. Мультисенсорные системы распознавания газов на основе металло-оксидных тонких пленок и наноструктур / В.В. Сысоев. - Автореф. дисс. на соиск. уч. степ. докт. тех. наук. - Саратов, 2009. - 35 с.

4. Fleischmann C., Lievenbrück M., Ritter H. Polymers and dyes: developments and applications. Polymers, 2015, v. 7, № 4, p. 717-746.

5. Dollendorf C., Kreth S.K., Choi S.W., Ritter H. Polymerization of novel methacrylated anthraquinone dyes. Beilstein J. Org. Chem., 2013, v. 9, № 2, p. 453-459.

6. Demetriou M., Krasia-Christaforou T., Well-defined diblock copolymers possessing fluorescent and metal chelating functionalities as novel macromoleculare sensors for amines. Journal of Polymer Science. Part A: Polymer Chemistry, 2012, v. 50, № 1, p. 52-60.

7. Voss G., Drechsler M., Eller S., Gradzielski M., Gunzelmann D., Mondal S., Van Smaalen S., Voertler C.S. Polymeric colorants: statistical copolymers of indigo building blocks with defined structures. Helv. Chim. Acta., 2009, v. 92, № 12, p. 2675-2697.

8. Tan H., Pan C., Wang G., Wu Y., Zhang Y., Chen X., Zou Y., Yu G., Zhang M. Synthesis and characterization of conjugated polymers with main-chain donors and pendent acceptors for dye-sensitized solor cells. RSC Adv., 2013, v. 3, № 37, p. 16612-16618.

9. Lenahan K.M., Wang Y.-X., Liu Y., Clans R.O., Heflin J.R., Marciu D., Figura C. Novel polymer dyes for nonlinear optical applications using ionic self-assembled monolayer technology. Advanced Materials, 1999, v. 10, № 11, p. 853-855.

10. Lewis A.L. Synthesis of fluorescently labeled biocompatible polymers. Biomacromolecules, 2011, v. 12, № 6, p. 2225-2234.

11. Шапиро Б.И., Исаева А.Н., Тверской В.А. Матричный синтез агрегатов карбоцианиновых красителей на катионных полимерах. Российские нанотехнологии, 2010, т. 5, № 7-8, с. 35-40.

12. Akceylan E., Bahadir M., Yilmaz M. Removal afficiency of a calyx[4]arene-based polymer for water-soluble carcinogenic direct azo dyes and aromatic amines. J. Hazard Mater. 2009, v. 162, № 2-3, p. 960-966.

13. Saja V.S., Zong K., Pyo M. NIR-absorbing poly(thieno[3,4-b]thiophene-2-carboxylic acid) as polymer due for dye-sensitized solar cells. J. Photochem. and Photobiol. A, 2010, v. 212, № 2-3, p. 81-87.

14. Solpan D., Guran S., Saraydin D., Güven O. Adsorption of methyl violet in aqueous solutions by poly (acrylamide-cj-acrylic acid) hydrogels. Radiat. Phys. Chem., 2003, v. 66, № 2, p. 117-127.

15. Соборовер Э.И., Тверской В.А., Токарев С.В. Оптический химический сенсор диоксида серы на основе пленок функциональных полимеров для контроля воздуха рабочей зоны. Сополимеры полидиметилсилоксанов с ионосвязанным катионом бриллиантового зеленого. Журнал аналитической химии, 2005, т. 60, № 5, с. 507-513.