Design scheme for the assessment of storage and loss moduli depending on the chemical structure of the polymer and the composition of the mixture
https://doi.org/10.35164/0554-2901-2017-1-2-25-28
Abstract
The calculation model for prediction both of storage and loss moduli is suggested. Consideration is made on the basis of the atomic constants that take into account the contribution of each atom and the polar group in the van der Waals volume and shear modulus at high frequencies. The relations obtained allow us to calculate the shear modulus, storage modulus, and loss modulus as a function of frequency, temperature and molecular weight distribution.
About the Authors
Т. Мацеевич
Московский Государственный строительный университет
Russian Federation
Russian Federation
А. Аскадский
Московский Государственный строительный университет; Институт элементоорганических соединений им. А.Н. Несмеянова РАН
Russian Federation
Russian Federation
М. Петунова
Институт элементоорганических соединений им. А.Н. Несмеянова РАН
Russian Federation
Russian Federation
О. Коврига
Институт элементоорганических соединений им. А.Н. Несмеянова РАН
Russian Federation
Russian Federation
М. Попова
Московский Государственный строительный университет
Russian Federation
Russian Federation
References
1. A.A. Askadskii. Physical properties of Polymers. Prediction and Control. Gordon and Breach Publishers, Amsterdam, 1996, 336 pp.
2. А.А. Аскадский, В.И. Кондращенко. Компьютерное материаловедение полимеров. Т.1. Атомно-молекулярный уровень. М.: Научный Мир, 1999, 544 стр.
3. A.A. Askadskii. Computational Materials Science of Polymers, Cambridge International Science Publishing, Cambridge, 2003, 696 pp.
4. А.А. Аскадский, Ю.И. Матвеев. Химическое строение и физические свойства полимеров. М.: Химия, 1983, 240 стр.
5. V.R. Raju, G.G. Smith, G. Marin, J.R. Knox, W.W. Graessley. Journal of Polymer Sci., Polymer Physics Edition, Vol. 17., 1183-1195 (1979).
6. W.E. Rochefort, G.G. Smith, H. Rachapudy, V.R. Raju, and W.W. Graessley. Journal of Polymer Sci., Polymer Physics Edition, Vol. 17. 1197-1210 (1979).
7. Г.В. Виноградов, А.Я. Малкин, Ю.Г. Яновский и др. // Высокомолек. соед., 14А, № 11, Vysokomol. Soedin., 1972, 14A, № 11, 2425-2442.
8. Seung-Yeop Kwak, Jeongsoo Choi, and Hee Jae Song. Chem. Mater., Vol. 17, 1148-1156 (2005).
9. Cattaleeya Pattamaprom, Ronald G. Larson, Anuvat Sirivat. Rheol. Acta, 47, 689-700 (2008).
10. V.R. Raju, H. Rachapudy, W.W. Graessley. Journal of Polymer Sci., Polymer Physics Edition, Vol. 17., 1223-1235 (1979).
11. Chenyang Liu, Jian Yu, Jiasong He., et all., Macromolecules, Vol. 37, 9279-0282 (2004).
12. А.А. Аскадский. Деформация полимеров.М.: Химия, 1973, 448 стр.
13. A.Ya. Malkin, A.I. Isayev. Rheology: conceptions, methods, applications. ChemTec Publishing, Toronto, 2005. 558 pp.
Review
For citations:
, , , , Design scheme for the assessment of storage and loss moduli depending on the chemical structure of the polymer and the composition of the mixture. Plasticheskie massy. 2017;(1-2):25-28. (In Russ.) https://doi.org/10.35164/0554-2901-2017-1-2-25-28
Views:
432
Email this article 
