Radical copolymerization of acrylic acid and methoxy oligo(ethylene glycol) methacrylate in aqueous solutions
https://doi.org/10.35164/0554-2901-2017-1-2-6-8
Abstract
Сomposition diagrams for the radical homogeneous copolymerization of acrylic acid and methoxy oligo(ethylene glycol) methacrylate (with the degree of ethoxylation of 23) in aqueous solutions were obtained. For low conversions (less than 10%), the resulting copolymers were found to be enriched with methacrylic ester units for all initial comonomer ratios. Using Mayo-Lewis, Fineman-Ross and Kelen-Tüdös methods the reactivity ratios of acrylic acid (0.02-0.07) and methoxy oligo(ethylene glycol) methacrylate (1.14-1.20) were determined.
About the Authors
Д. Kamorin
Нижегородский государственный технический университет им. Р.Е. Алексеева; Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского
Russian Federation
Russian Federation
К. Shirshin
Нижегородский государственный технический университет им. Р.Е. Алексеева; ФГУП «Научно-исследовательский институт химии и технологии полимеров имени академика В.А. Каргина с опытным заводом»
Russian Federation
Russian Federation
Д. Orekhov
Нижегородский государственный технический университет им. Р.Е. Алексеева
Russian Federation
Russian Federation
А. Sivokhin
Нижегородский государственный технический университет им. Р.Е. Алексеева
Russian Federation
Russian Federation
А. Sadikov
Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского
Russian Federation
Russian Federation
О. Kazantsev
Нижегородский государственный технический университет им. Р.Е. Алексеева; Национальный исследовательский Нижегородский государственный университет им. Н.И. Лобачевского
Russian Federation
Russian Federation
Е. Panina
Нижегородский государственный технический университет им. Р.Е. Алексеева
Russian Federation
Russian Federation
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Review
For citations:
Kamorin , Shirshin , Orekhov , Sivokhin , Sadikov , Kazantsev , Panina Radical copolymerization of acrylic acid and methoxy oligo(ethylene glycol) methacrylate in aqueous solutions. Plasticheskie massy. 2017;(1-2):6-8. (In Russ.) https://doi.org/10.35164/0554-2901-2017-1-2-6-8
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