Modification of low molecular weight polyethylene with maleic anhydride and chitosan
https://doi.org/10.35164/0554-2901-2024-06-40-42
Abstract
Modification of lowmolecularweight polyethylene with maleic anhydride and synthesis of grafted copolymer of low-molecularweight polyethylene with maleic anhydride and chitosan in melt using radical polymerization initiator were carried out under shear field conditions. The fact of copolymer formation was confirmed by elemental analysis and IR spectroscopy data. The synthesized copolymers can be used to obtain compositions of polyethylene with chitosan. Their presence contributes to an increase in the melt flow index, which leads to an improved distribution of particles of dispersed phase in the composition and manufacturability of its processing.
About the Authors
A. M. FutoryanskayaRussian Federation
Moscow
V. O. Kudyshkin
Uzbekistan
Tashkent
References
1. Акопова Т.А. Твердофазный синтез, структура, свойства и перспективы применения материалов на основе полисахарида хитозана: дисс. докт. хим. наук. М.: 2013. 284 с.
2. Rogovina S., Aleksanyan K., Vladimirov L. et al. Development of Novel Biodegradable Polysaccharide-Based Composites and Investigation of Their Structure and Properties // J Polym Environ. 2018. V. 26. P. 1727–1736. DOI: 10.1007/s10924-017-1069-3.
3. Vasilyev I.Y., Ananyev V.V., Kolpakova V.V., Sardzhveladze A.S. Development of technology for producing biodegradable hybrid composites based on polyethylene, starch and monoglycerides // Fine. Chem. Technol. 2020. V. 15, N6. P. 44–55. https://doi.org/10.32362/2410-6593-2020-15-6-44-55.
4. Vasil’ev I.Y., Anan’ev V.V., Sultanova Y.M., Kolpakova V.V. The Influence of the Composition of Polyethylene, Starch and Monoglyceride Biodegradable Compositions on Their Physicomechanical Properties and Structure // Polym. Sci. Ser. D. 2022. V. 15, N1. P. 122–127. https://doi.org/10.1134/S1995421222010257.
5. Beg M.D.H., Kormin S., Bijarimi M., Zaman H.U. Preparation and Characterization of Low-Density Polyethylene/Thermoplastic Starch Composites // Adv. Polym. Technol. 2016. V. 35. Р. 21521. https://doi.org/10.1002/adv.21521.
6. Xianru He, Shirong Z., Guangsu H., Yaoqiang R. Solution Grafting of Maleic Anhydride on Low-Density Polyethylene: Effect on Crystallization Behavior // Journal of Macromolecular Science, Part B: Physics. 2013. V. 52. P. 1265–1282. https://doi.org/10.1080/00222348.2013.764217.
7. Зеленецкий А.Н., Сизова М.Д., Волков В.П., Зеленецкий С.Н., БолдуевВ.С. Модификация полиолефинов методами реактивной экструзии: сравнение расплавной и твердотельной модификации, проводимой на одинаковом оборудовании // Пластические массы. 2019. №11–12. С. 21–26. DOI: 10.35164/0554-2901-2019-11-12-21-26.
8. Tahseen A.S. Reactive melt blending of low-density polyethylene with poly (acrylic acid) // Arabian Journal of Chemistry. 2015. V. 8. N2. P. 191–199. https://doi:10.1016/j.arabjc.2011.05.021.
9. Шейпак Т.М., Горбачев А.А., Третинников О.Н. Сорбция ионов цинка нетканым материалом из полипропилена, модифицированным полиакриловой кислотой, привитой к поверхности волокна: роль плотности прививки и водородных связей // Высокомолек. соед. А. 2018. Т 60, №4. С. 284–288.
10. Kudyshkin V.O., Bozorov N.I., Ashurov N. Sh., Ashurov N.R., Rashidova S.Sh. On the Application of Modified Low Molecular Weight Polyethylene in Compositions with Starch // Russ. J. Appl. Chem. 2021. V. 94. P. 947–953. https://doi.org/10.1134/S1070427221070120.
11. Kudyshkin V.O., Bozorov N.I., Ashurov N.Sh., Ashurov N.R., Rashidova S.Sh. Structure and properties of compositions of linear low-density polyethylene with starch // Polymers for Advanced Technologies. 2023. P. 1172–1756. DOI: 10.1002/pat.6008.
Review
For citations:
Futoryanskaya A.M., Kudyshkin V.O. Modification of low molecular weight polyethylene with maleic anhydride and chitosan. Plasticheskie massy. 2024;(6):40-42. (In Russ.) https://doi.org/10.35164/0554-2901-2024-06-40-42