Preview

Plasticheskie massy

Advanced search

Features of oxidative dehydropolycondensation of 2,6-dimethylphenol in the presence of copper-amine catalytic complexes

https://doi.org/10.35164/0554-2901-2024-05-23-25

Abstract

The relative activity of copper-amine catalytic complexes in the oxidative dehydropolycondensation of 2,6-dimethylphenol has been compared. The influence of the composition and concentration of the catalytic complex on the polycondensation reaction and the molecular weight of the resulting poly-2,6-dimethyl-1,4-phenylene oxide has been investigated. The influence of the nature of solvents on the molecular weight index of the formed polymer is considered.

About the Authors

М. N. Lyoshina
Homa Сompany
Russian Federation

Dzerzhinsk



K. V. Shirshin
Homa Сompany; Nizhny Novgorod State Technical University named after R.E. Alekseev
Russian Federation

Dzerzhinsk

Nizhny Novgorod



N. V. Zaytsev
CJSC Himgazservice
Russian Federation

Moscow



References

1. Михайлин Ю.А. Термоустойчивые полимеры и полимерные материалы. СПб: Профессия. 2006. 624 с.

2. Ли Г., Стоффи Д., Невилл К. Новые линейные полимеры. / пер. с англ. Я.С. Выгодского. М.: Химия. 1972. 280 с.

3. Лёшина М.Н., Ладилова Н.Ю, Корниенко П.В., Ширшин К.В., Удут В.Н., Зайцева Н.В., Дунаев Д.Г., Виноградов Н.Е. Способ получения поли-2,6-диметил-1,4-фениленоксида / Патент РФ, МПК C08G65/44 C08F2/06, RU 2806582 (подано 2023-01-30, опубл. 2023-11-01).

4. Yoshida Kioyoshi I, Ohsaki Naoto, Fuji Hiroya. Process for producing polyphenylene ether / U.S. Patent, IPC C08J11/02, US 6759507В1, (Publication date 06.07.2004).

5. Бюллер К.-У. [Büller] Тепло- и термостойкие полимеры / Перевод с нем. Н. В. Афанасьева, Г.М. Цейтлина. М.: Химия.1984. 1056 с.


Review

For citations:


Lyoshina М.N., Shirshin K.V., Zaytsev N.V. Features of oxidative dehydropolycondensation of 2,6-dimethylphenol in the presence of copper-amine catalytic complexes. Plasticheskie massy. 2024;(5):23-25. (In Russ.) https://doi.org/10.35164/0554-2901-2024-05-23-25

Views: 304


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0554-2901 (Print)