Mechanism of initiation of ethylene cationic polymerization in the presence of an aluminum chloride aquacomplex in heptane with a stoichiometric composition of 1:1:1:2 at the quantum level
https://doi.org/10.35164/0554-2901-2024-01-24-26
Abstract
In this paper, the mechanism of ethylene initiation in the presence of an aluminum chloride – water catalyst in a heptane solvent of stoichiometric composition 1:1:1:2 was studied using the ab initio RHF theoretical quantum chemical method. The activation energy and thermal effect of this reaction were obtained. These data can be useful for further research in the field of cationic polymerization, and can also be used in the development of new technological processes of polyethylene with specified physicochemical properties characteristic of fiber optics.
About the Authors
V. A. Babkin
Sebryakovsky branch of Volgograd State Technical University
Russian Federation
Russian Federation
Volgograd region, Mikhaylovka
D. S. Andreev
Sebryakovsky branch of Volgograd State Technical University
Russian Federation
Russian Federation
Volgograd region, Mikhaylovka
A. V. Ignatov
Sebryakovsky branch of Volgograd State Technical University
Russian Federation
Russian Federation
Volgograd region, Mikhaylovka
M. I. Artsis
N .M. Emanuel Institute of Biochemical Physics of the Russian Academy of Sciences
Russian Federation
Russian Federation
Moscow
V. S. Belousova
I.M. Sechenov First Moscow State Medical University
Russian Federation
Russian Federation
Moscow
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Review
For citations:
Babkin V.A., Andreev D.S., Ignatov A.V., Artsis M.I., Belousova V.S. Mechanism of initiation of ethylene cationic polymerization in the presence of an aluminum chloride aquacomplex in heptane with a stoichiometric composition of 1:1:1:2 at the quantum level. Plasticheskie massy. 2024;(1):24-26. (In Russ.) https://doi.org/10.35164/0554-2901-2024-01-24-26
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