Контролируемый синтез и свойства растворов сополимеров метакриловых эфиров и аммоний-содержащего метакриламида

Методом радикальной полимеризации с обратимой передачей цепи по механизму «присоединение-фрагментация» с высокими выходами и в контролируемом режиме получены сополимеры на основе олиго(этиленгликоль)метакрилата, додецилметакрилата и катионного мономера N-метакрилоиламинопропил-N,N-диметил-N-пропиламмоний бромида. Показано влияние состава полученных полимеров на растворимость в воде и органических растворителях, распределение в системе вода-октанол и межфазное натяжение на границе «вода-масло». Обнаружено наличие термочувствительных свойств для полимеров в воде, а также исследована их агрегация в водных средах.

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