Amphiphilic properties of 2-(acrylamido)dodecanesulfonic acid and its water-soluble copolymers with alkoxyoligo(ethylene glycol)methacrylates
https://doi.org/10.35164/0554-2901-2023-7-8-26-30
Abstract
The surface-active properties (in aqueous solutions and water-hexane mixtures) of the amphiphilic sulfo-containing macromonomer 2-(acrylamido)dodecanesulfonic acid (AAС12SА) were studied; copolymers of this surfomer with oligo(ethylene glycol)methacrylates were synthesized. Тhe effect of the content of sulfonic units in the obtained molecular brushes on their thermosensitive properties in water and water-salt solutions was determined.
About the Authors
M. V. Savinova
Nizhny Novgorod State Technical University n.a. R.E. Alekseev
Russian Federation
Russian Federation
Nizhny Novgorod
I. R. Arifullin
Nizhny Novgorod State Technical University n.a. R.E. Alekseev
Russian Federation
Russian Federation
Nizhny Novgorod
O. A. Kazantsev
Nizhny Novgorod State Technical University n.a. R.E. Alekseev
Russian Federation
Russian Federation
Nizhny Novgorod
M. N. Chubenko
Nizhny Novgorod State Technical University n.a. R.E. Alekseev
Russian Federation
Russian Federation
Nizhny Novgorod
N. S. Kamorina
Nizhny Novgorod State Technical University n.a. R.E. Alekseev
Russian Federation
Russian Federation
Nizhny Novgorod
E. A. Timchenko
Nizhny Novgorod State Technical University n.a. R.E. Alekseev
Russian Federation
Russian Federation
Nizhny Novgorod
References
1. Badi, N. Non-linear PEG-based thermoresponsive polymer systems / N. Badi // Prog. Polym. Sci. – 2017. – Vol. 66. – P. 54–79. 2. Liu, M. Conformation-function relationships for the comb-shaped polymer pOEGMA / M. Liu, J.C. Leroux, M.A. Gauthier // Prog. Polym. Sci. –2015. – Vol. 48. – P. 111–121.
2. Orekhov, D.V. Molecular brushes based on copolymers of alkoxy oligo(ethylene glycol) methacrylates and dodecyl(meth) acrylate: features of synthesis by conventional free radical polymerization / D.V. Orekhov, D.M. Kamorin, A.S. Simagin // Polymer Bulletin. – 2021. – Vol. 78. – P. 5833–5850.
3. Sivokhin, A.Р. Amphiphilic thermoresponsive copolymer bottlebrushes: synthesis, characterization, and study of their selfassembly into flower-like micelles / A.Р. Sivokhin, D.V. Orekhov, O.A. Kazantsev et al. // Polymer Journal. – 2021. – Vol. 53. – Р. 655–665.
4. Lutz, J.-F. Thermo-Switchable Materials Prepared Using the OEGMA-Platform / J.-F. Lutz // Adv. Mater. – 2011. – Vol. 23, N19. – P. 2237–2243.
5. Matsumoto, M. Self-assembly of amphiphilic block pendant polymers as microphase separation materials and folded flower micelles / M. Matsumoto, M. Takenaka, M. Sawamoto, T. Terashima // Polym. Chem. – 2019. – Vol. 10. – P. 4954–4961.
6. Sun, L. Synthesis of polymeric micelles with dual-functional sheddable PEG stealth for enhanced tumor-targeted drug delivery / L. Sun, H. Wei, X.S. Zhang et al. // Polym. Chem. – 2020. – Vol. 11. – P. 4469–4476.
7. Cho, H.Y. Synthesis of Poly(OEOMA) Using Macromonomers via “Grafting-Through” ATRP / H.Y. Cho, P. Krys, K. Szczesniak et al. // Macromolecules. – 2015. – Vol. 48, N18. – P. 6385–6395.
8. Ильгач, Д.М. Использование методов контролируемой радикальной полимеризации для синтеза полимерных щеток / Д.М. Ильгач, Т.К. Мелешко, А.В. Якиманский // Высокомолекулярные соединения. Серия C. – 2015. – Т. 57, №1. – С. 6–24.
9. Pelras, T. Synthesis and applications of compartmentalised molecular polymer brushes / T. Pelras, C.S. Mahon, M. Mullner // Angewandte Chemie International Edition. – 2018. – Vol. 57, N 24. – P. 6982–6994.
10. Orekhov, D.V. Assembly of oligo(ethylene glycol)- and amine-containing methacrylic esters in water and water-hexane mixtures / D.V. Orekhov, D.M. Kamorin, M. Rumyantsev et al. // Colloids and Surfaces A: Physicochemical and Engineering Aspects. – 2015. – Vol. 481. – P. 20–30.
11. Орехов, Д.В. Амфифильные свойства алкоксиолигоэтиленгликольметакрилатов и сополимеров на их основе / Д.В. Орехов, К.В. Ширшин, М.В. Савинова и др. // Пластические массы. – 2019. – №7-8. – С. 38–41. 13. Goh, E. Cross-Linked Poly(methacrylic acid-co-poly(ethylene oxide) methyl ether methacrylate) Microspheres and Microgels Prepared by Precipitation Polymerization: A Morphology Study / E. Goh, H. Stöver // Macromolecules. – 2002. – Vol. 35, N 27. – P. 9983–9989.
12. Куренков В.Ф. Полиакриламидные флокулянты // Соровский образовательный журнал. – 1997. – №7. – С. 55–63.
13. Куренков, А.В. Седиментация суспензии каолина сополимерами 2-акриламидо-2-метилпропансульфоната натрия с акрилатом натрия / А.В. Куренков, В.Ф. Куренков, Ф.И. Лобанов // Журнал прикладной химии. – 2009. – Т. 82, №11. – С. 1894–1898.
14. Bouhamed, H. Alumina interaction with AMPS–MPEG copolymers produced by RAFT polymerization: Stability and rheological behavior / H. Bouhamed, S. Boufi, A. Magnin // Journal of Colloid and Interface Science. – 2009. – Vol. 333, N1. – P. 209–220.
15. Erzengin, S. G. Applications of sulfonate-carboxylate copolymers in cement / S.G. Erzengin, A. Bodur, S.P. Ozkorucuklu et al. // Advances in Cement Research. – 2016. – Vol. 28, N 10. – P. 630–642.
16. Xue, J. The Development and Application of the Acrylamide Kind Polymers for Tertiary Oil Recovery in China / J. Xue, D. Guo, Q. Hou // International Journal of Petroleum Technology. – 2018. – Vol. 5. – P. 19–29.
17. Якимцова, Л.Б. Термическая устойчивость сополимеров метакриламида и 2-акриламидо-2-метилпропансульфоната натрия / Л.Б. Якимцова, П.А. Никишев, А.П. Бочко // Полимерные материалы и технологии. – 2020. – Т. 6, №3. – С. 60–65.
18. Chen, L. Experimental study of calcium-enhancing terpolymer hydrogel for improved oil recovery in ultrodeep carbonate reservoir / L. Chen, X. Zhu, M. Fu et al. // Colloids and Surfaces A: Physicochemical and Engineering Aspects. – 2019. – Vol. 570. – P. 251–259.
19. Cai, S. Molecular interaction of poly (acrylamide‐co‐2‐acrylamido‐ dodecyl sulfonate) with dual responsiveness and application in oily emulsion wastewater / S. Cai, Y. Wang, X. He // Journal of Applied Polymer Science. – 2021. – Vol. 139, N 4. – P. 51528.
20. Sun, J. Synthesis and evaluation of a novel hydrophobically associating polymer based on acrylamide for enhanced oil recovery / J. Sun, W. Du, X. Pu et al. // Chemical Papers. – 2015. – Vol. 69, N12. – P. 1598–1607.
21. Wu, X. Self-assembly of a series of random copolymers bearing amphiphilic side chains / X. Wu, Y. Qiao, H. Yang, J. Wang // Journal of Colloid and Interface Science. – 2010. – Vol. 349, N2. – P. 560–564.
Review
For citations:
Savinova M.V., Arifullin I.R., Kazantsev O.A., Chubenko M.N., Kamorina N.S., Timchenko E.A. Amphiphilic properties of 2-(acrylamido)dodecanesulfonic acid and its water-soluble copolymers with alkoxyoligo(ethylene glycol)methacrylates. Plasticheskie massy. 2023;1(7-8):26-30. (In Russ.) https://doi.org/10.35164/0554-2901-2023-7-8-26-30
Views:
182
Email this article 
