Biodegradable composite material based on the starch-g-vinyl acetate copolymer
https://doi.org/10.35164/0554-2901-2022-7-8-20-22
Abstract
A native potato starch was modififi ed with vinyl acetate by graft polymerization in alkaline medium with pH 10 in the mode of temperature change from 70 to 80°C for 4 hours. The initiator of the process was ammonium persulfate (NH4)2S2O8. The conversion of vinyl acetate was 91,5%. The chemical structure of graft copolymer (Starch:Vinyl acetate) was confifi rmed by IR-spectroscopy. Composite materials of modififi ed starch and triethyl citrate with tensile strength of 24 MPa were obtained. Under natural environmental conditions, materials undergo biodegradation of 96% in 28 days.
About the Authors
A. P. MONINARussian Federation
Nizhny Novgorod
K. V. APRYATINA
Russian Federation
Nizhny Novgorod
O. N. SMIRNOVA
Russian Federation
Nizhny Novgorod
L. A. SMIRNOVA
Russian Federation
Nizhny Novgorod
References
1. Haider Tobias P., Völker C., Kramm J., Landfester K., Wurm F. R. // Angewandte Chemie. – 2018. – Vol. 58. – №1. – P. 50–62.
2. Dris R., Agarwal S., Laforsch Ch. Plastics: From a Success Story to an Environmental Problem and a Global Challenge // Global Challenges. – 2020. – Vol. 4. – №6.
3. Gomiero A. Plastics in Environment. – Books on Demand, 2019.
4. Teixeira-Costa B. E., Andrade C. T. // Polysaccharides. – 2022. – Vol. 3. – №1. – P. 32–58.
5. Vilar M. Starch-Based Materials in Food Packaging: Processing, Characterization and Applications. – Academic Press, 2017.
6. Ashogbon A. O., Akintayo E. T. // Starch. – 2014. – Vol. 66. – №1–2. – P. 41–57.
7. Khalil M.I., Mostafa Kh.M., Hebeish A. // Die Angewandte Makromolekulare Chemie. – 1993. – Vol. 213. – №1. – P. 43–54.
8. Amann M., Minge O. Biodegradability of Poly(vinyl acetate) and Related Polymers // Advances in Polymer Science. – 2012. – Vol. 245.
9. Haroon M., Wang L., Yu H., Abbasi N.M., Abdin-ul-Z., Saleem M., Khan R.U., Ullah R.S., Chen Q., Wu J. // RSC Advances. – 2016. – №82. – P. 78264–78285.
10. Pang Ch., Shanks R.A., Daver F. // Composites: Part A. – 2015. – Vol.70. – P. 52–58.
11. Lin D., Huang Y., Liu Y., Luo T., Xing B., Yang Y., Yang Z., Wu Z., Chen H., Zhang Q., Qin W. // LWT – Food Science and Technology. – 2018. – Vol. 96. – P. 704–712.
12. Le Bolay N., Molina-Boisseau S. // Powder Technology. – 2013. – Vol. 255. – P. 36–43.
13. Junlapong K., Boonsuk Ph., Chaibundit Ch., Chantarak S. // International Journal of Biological Macromolecules. – 2019. – Vol. 137. – P. 521–527.
14. Ali S. S., Tang X., Alavi S., Faubion J. // Journal of Agricultural and Food Chemistry. – 2011. – Vol. 59. – №23. – P. 12384–12395.
Review
For citations:
MONINA A.P., APRYATINA K.V., SMIRNOVA O.N., SMIRNOVA L.A. Biodegradable composite material based on the starch-g-vinyl acetate copolymer. Plasticheskie massy. 2022;(7-8):20-22. (In Russ.) https://doi.org/10.35164/0554-2901-2022-7-8-20-22