Regularities of the radical copolymerization of dodecyl (meth) acrylate and a new cationic monomer N-(dibutylaminomethyl) methacrylamide
https://doi.org/10.35164/0554-2901-2021-9-10-18-21
Abstract
The regularities of radical copolymerization of dodecyl methacrylate (DMA) or dodecyl acrylate (DA) with a new cationic monomer - N-(dibutylaminomethyl) methacrylamide (DBAMMA) in toluene solutions were determined. The copolymers formed at low conversions in the DMA-DBAMMA system are enriched in ether units, and in the DA-DBAMMA system - in aminoamide units. The relative activities of comonomers determined by the Feineman-Ross and Kehlen-Tudosh methods in the first case were 1.56-1.60 (DMA) and 0.87-0.89 (DBAMMA), in the second case - 0.53-0.64 (DA) and 0.80-0.90 (DBAMMA).
About the Authors
I. R. Arifullin
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
Nizhny Novgorod
K. V. Shirshin
Nizhny Novgorod State Technical University; V.A. Kargin Polymer Chemistry and Technology Research Institute
Russian Federation
Russian Federation
Nizhny Novgorod
Dzerzhinsk, Nizhny Novgorod region
O. A. Kazantsev
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
Nizhny Novgorod
M. V. Savinova
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
Nizhny Novgorod
T. A. Ryabova
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
Nizhny Novgorod
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Review
For citations:
Arifullin I.R., Shirshin K.V., Kazantsev O.A., Savinova M.V., Ryabova T.A. Regularities of the radical copolymerization of dodecyl (meth) acrylate and a new cationic monomer N-(dibutylaminomethyl) methacrylamide. Plasticheskie massy. 2021;(9-10):18-21. (In Russ.) https://doi.org/10.35164/0554-2901-2021-9-10-18-21
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