Preview

Plasticheskie massy

Advanced search

Non-combustible, optically transparent polycarbonate compositions

https://doi.org/10.35164/0554-2901-2020-9-10-28-30

Abstract

A brief review of the results of research on reducing the flammability of modified materials based on polycarbonate, the effect of flame retardants and additives that reduce dropping, as well as affecting the complex of properties of polycarbonate is presented. The optimal concentrations of modifying additives for obtaining fire-resistant compositions with high optical characteristics have been determined. It is shown that to achieve the maximum flammability category (PV-0 at a thickness of 2 mm) and oxygen index (42.3%) for thin-walled products, it is necessary to use a high- viscosity grade of polycarbonate (MFI 2.5±1.0 g/10 min), alkali metal sulfonates as a fire retardant and an anti-dripping additive.

About the Authors

I. U. Zolkina
Institute of Plastics named after G.S. Petrov Joint Stock Company (Institute of Plastics JSC)
Russian Federation


S. A. Radzinsky
Institute of Plastics named after G.S. Petrov Joint Stock Company (Institute of Plastics JSC)
Russian Federation


T. I. Andreeva
Institute of Plastics named after G.S. Petrov Joint Stock Company (Institute of Plastics JSC)j
Russian Federation


D. Kh. Safin
Organichesky Sintez Kazan Joint Stock Company (Kazanorgsintez PJSC)
Russian Federation


A. V. Presnyakov
Organichesky Sintez Kazan Joint Stock Company (Kazanorgsintez PJSC)
Russian Federation


A. R. Validov
Organichesky Sintez Kazan Joint Stock Company (Kazanorgsintez PJSC)
Russian Federation


I. D. Simonov-Emelianov
MIREA – Russian Technological University (Lomonosov Institute of Fine Chemical Technologies)
Russian Federation


References

1. Патент 2049358 (ФРГ).

2. J. of Polymer Sci., Polymer Chem. Ed., 1980, 18, №2, р. 245.

3. Патент 4195156 (США).

4. Заявка 54-85-247 (Япония).

5. Flame Retard Polym. Mater. V. 1, 2. Eds., Kuryla WS. Papa AG NewJork, 1973, p. 344.

6. J. Polymer Mater, 1974, 3, N 2, p. 81–98.

7. Патент 3855277 (США).

8. Заявка 2115552 (ФРГ).

9. Патент 1495968 (Великобритания).

10. Патент 3919617 (США).

11. Патент 4039509 (США).

12. Патент 52-125121 (Япония).

13. Патент 52-125132 (Япония).

14. Высокомолек. соед., 1968, ХА, с. 1103.

15. Родэ В./ Новые поликонденсационные полимеры/ М.: Мир, 1969, с. 207–272.

16. Carter R.P., Reiner G.E. / Tech. Conf. Soc. Plast. Eng. NY Sect./ 1980, p. 5–8.

17. Thomas L.S., Ogoe S.A. Tech. Conf. Sac. Plast. Eng., Baltimor – Washington Sect, 1985, p. 1000–1002.

18. Weil E.D. and Choudhary V./ J. of Fire Sciences/ (1995)13, p. 104–126.

19. Lu S.Y., Hamerton I. /Recent developments in the chemistry of halogen-free fl ame retardant polymers. / Prog Polym Sci/ 2002/ 27:1661- 712.

20. Ishli K., Shimomai K. /Flame-retardent polycarbonate resin composition and a molded product/ US Patent 6342550, 2002.

21. Periadurai T., Vijayakumarb C.T., Balasubramanian M/ Thermal decomposition and fl ame retardant behavior of SiO2-phenolic nanocomposite/ J. Anal Appl Pyrol. 2010;89:244-9.

22. Yuan D.D., Yin H.Q., Cai X.F./ Eff ect of a novel fl ame retardant containing silicon and nitrogen on the thermal stability and fl ame retardancy of polycarbonate/ J. Therm Anal Calorim. 2012.

23. Schnell Н. / Angwe. Chem., 68 (1956) 633–640.

24. Schell H. / Polym. Rev. 9 (1964).

25. Михайлов Ю.А. / Тепло-, термо- и огнестойкость полимерных материалов/ СПб.: НОТ, 2011 г., с. 216–221.

26. Hugard M ./ J. of Fire Sciences/ (1996)14, p. 393–408.

27. Green G. / J. of Fire Sciences/ (1996)14, p. 426–442.

28. Schell H. / Ind. Ehg. Chem. 51 (1959) 157.


Review

For citations:


Zolkina I.U., Radzinsky S.A., Andreeva T.I., Safin D.Kh., Presnyakov A.V., Validov A.R., Simonov-Emelianov I.D. Non-combustible, optically transparent polycarbonate compositions. Plasticheskie massy. 2020;(9-10):28-30. (In Russ.) https://doi.org/10.35164/0554-2901-2020-9-10-28-30

Views: 541


Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 License.


ISSN 0554-2901 (Print)