The influence of solid-phase fire retardants on the physical and mechanical properties of intumescent polymer materials based on plasticized polyvinyl chloride
https://doi.org/10.35164/0554-2901-2025-06-3-8
Abstract
The paper presents the results of a study of changes in the physical and mechanical properties of polymer materials based on plasticized polyvinyl chloride of various compositions with the introduction of solid-phase flame retardants during extrusion processing. A mixture of oxidized graphite and ultrafine aluminum hydroxide was used as a complex flame retardant. Several key factors influencing the changes in physical and mechanical properties have been identified: the molecular weight of the polymer, the content of low and high molecular weight plasticizer, and the granulometric composition of oxidized graphite in a complex flame retardant.
About the Authors
A. A. Galiguzov
Lomonosov Moscow State University
Russian Federation
Russian Federation
A. A. Serdan (jr.)
Lomonosov Moscow State University
Russian Federation
Russian Federation
N. V. Yashin
Lomonosov Moscow State University
Russian Federation
Russian Federation
V. V. Avdeev
Lomonosov Moscow State University
Russian Federation
Russian Federation
References
1. Галигузов А.А., Яшин Н.В., Авдеев В.В. Термостойкость огне защитных материалов на основе ПВХ-пластикатов различного состава // Пластические массы. 2023. №11–12. С. 21–25. DOI: 10.35164/0554-2901-2023-11-12-21-25.
2. Галигузов А.А., Сердан (младш.) А.А., Яшин Н.В., Авдеев В.В. Влияние состава ПВХ-пластиката на эксплуатационные свойства и огнезащитную эффективность полимерных материалов на его основе // Пожаровзрывобезопасность. 2023. Т. 32, №5. С. 26–39. DOI: 10.22227/0869-7493.2023.32.05.26-39.
3. Focke W.W., Muiambo H., Mhike W. Flexible PVC flame retarded with expandable graphite // Polymer Degradation and Stability. 2014. N100. P. 63–69. DOI: 10.1016/j.polymdegradstab.2013.12.024.
4. Lagreve C., Ferry L., Lopez-Cuesta J.-M. Flame Retardant Polymer Materials Design for Wire and Cable Applications. In: Flame Retardant Polymeric Materials. A Handbook. Ed. by Hu Y., Wang X. Boca Raton: Taylor and Francis Group. 2020. P. 294. DOI: 10.1201/b22345-14.
5. Carty P., White S. The effect of DOP plasticizer on smoke formation in poly(vinyl chloride) // Polymer. 1992. V. 33, N5. P. 1110–1111. DOI: 10.1016/0032-3861(92)90033-S.
6. Levchik S.V., Weil E.D. Overview of the recent literature on flame retardancy and smoke suppression in PVC // Polymers for Advanced Technologies. 2005. V.16, N10. P. 707–716. DOI: 10.1002/pat.645.
7. Архангельский И.В., Годунов И.А., Яшин Н.В., Нагановский Ю.К., Шорникова О.Н. Кинетика вспенивания терморасширяющихся огнезащитных составов // Пожаровзрывобезопасность. 2020. Т. 29, №5. С. 71–81. DOI: 10.22227/PVB.2020.29.05.71-81.
8. Yadav R., Singh M., Shekhawat D., Lee S.-Y., Park S.-J. The role of fillers to enhance the mechanical, thermal, and wear characteristics of polymer composite materials: A review // Composites Part A: Applied Science and Manufacturing. 2023. V. 175. P. 107775. DOI: 10.1016/j.compositesa.2023.107775.
9. Park S.-J., Seo M.-K. Element and Processing. In: Interface Science and Technology. Ed. by Ma M., Ji X.-X. 2011. V. 18. P. 431–499. DOI: 10.1016/B978-0-12-375049-5.00006-2.
10. Verma R., Rathod M.J., Goyal R.K. A review on the effect of processing techniques and functionalization of filler on mechanical properties of polymer nanocomposites // IOP Conference Series Materials Science and Engineering. 2020. V. 798, N1. P. 012031. DOI: 10.1088/1757-899X/798/1/012031.
11. Машляковский Л.Н., Лыков А.Д., Репин В.Ю. Органические покрытия пониженной горючести. Л.: Химия. 1989. 184 с. ISBN 5-7245-0304-2.
12. Glazkov S.S. A model of thermodynamic compatibility of the filler with the polymeric matrix in a composite // Russian Journal of Applied Chemistry. 2007. V. 80, P. 1594–1597. DOI: 10.1134/S1070427207090297.
13. Coaker A.W. Fire and flame retardants for PVC // Journal of Vinyl and Additive Technology. 2003. V. 9, N3. P. 108–115. DOI: 10.1002/vnl.10072.
14. Guler S.H., Simsek T., Guler O., Dikici B. Possible Interaction of PVC with Micro and Nano-fillers. In: Poly(Vinyl Chloride) Based Composites and Nanocomposites. Ed. by Akhina H., Sabu T. Cham: Springer. 2024. P. 335–360. DOI: 10.1007/978-3-031-45375-5_16.
15. Липатов Ю.С. Физическая химия наполненных полимеров. М.: Химия, 1977. С. 254.
16. Bi Q., Lu Y., Zhao C., Ma X., Khanal S., Xu S. A facile approach to prepare anhydrous MgCO3 and its effect on the mechanical and flame retardant property of PVC composites // Journal of Applied Polymer Science. 2021. V. 138. N45. P. 51349. DOI: 10.1002/app.51349.
17. Lu Y., Jiang N., Li X., Xu S. Effect of inorganic–organic surface modification of calcium sulfate whiskers on mechanical and thermal properties of calcium sulfate whisker/poly(vinyl chloride) composites // RSC Advances. 2017. N7. P. 46486–46498. DOI: 10.1039/C7RA09193A.
18. Gong J., Guo W., Wang K., Xiong J. Surface modification of magnesium hydroxide sulfate hydrate whiskers and its toughness and reinforcement for polyvinyl chloride // Polymer Composites. 2017. V. 39. N 10. P. 3676–3685. DOI: 10.1002/pc.24396.
19. Huang X.D., Goh S.H. Miscibility of C60-end-capped poly(ethylene oxide) with poly(vinyl chloride) // Polymer. 2002. V. 43. N4. P. 1417–1421. DOI: 10.1016/S0032-3861(01)00705-4.
20. Pan N., Guan D., He T., Wang R., Wyman I., Jin Y., Xia C. Remo val of Th4+ ions from aqueous solutions by graphene oxide // Journal of Radioanalytical and Nuclear Chemistry. 2013. V. 298. P. 1999–2008. DOI: 10.1007/s10967-013-2660-2.
21. Salvatore M., Carotenuto G., De Nicola S., Camerlingo C., Ambrogi V., Carfagna C. Synthesis and Characterization of Highly Intercalated Graphite Bisulfate // Nanoscale Research Letters. 2017. V. 12. P. 167. DOI: 10.1186/s11671-017-1930-2.
22. Rimkute G., Gudaitis M., Barkauskas J., Zarkov A., Niaura G., Gaidukevic J. Synthesis and Characterization of Graphite Intercalation Compounds with Sulfuric Acid // Crystals. 2022. V. 12, N3. P. 421. DOI: 10.3390/cryst12030421.
23. Madejova J., Gates W.P., Petit S. IR-Spectra of Clay Minerals. In: Developments in Clay Science. Ed. by Zhuang G., Yuan P. 2017. V. 8. P. 107–149. DOI: 10.1016/B978-0-08-100355-8.00005-9.
24. Лавров Н.А., Белухичев Е.В. Полимерные смеси на основе по ливинилхлорида (обзор) // Пластические массы. 2020. №3–4. С. 55–59. DOI: 10.35164/0554-2901-2020-3-4-55-59.
25. Milner P.W. Modification of PVC with NBR. In: Developments in Plastics Technology-4. Ed. by Whelan A., Goff J. P. Dordrecht: Springer. 1989. P. 99–137. DOI: 10.1007/978-94-009-1101-7_3.
26. Серенко О.А., Насруллаев И.Н., Баженов С.Л. Деформационные свойства полиэтилена средней плотности, наполненного частицами резины // Высокомолекулярные соединения. Серия А. 2003. Т. 45, №5. С. 759–766.
27. Серенко О.А., Баженов С.Л., Насруллаев И.Н., Берлин А.А. Влияние размера частиц на форму образующихся дефектов в дисперсно-наполненном композите // Высокомолекулярные со единения. Серия А. 2005. Т. 47, №1. С. 64–72. EDN: HSAFLN.
28. Гузеев В.В. Структура и свойства наполненного ПВХ. СПб.: Научные основы и технологии, 2012. С. 95–130. ISBN 978-5-91703-024-1.
29. Краускопф Л.Г., Годвин А. Получение, добавки и наполнители, сополимеры, свойства, переработка. Под ред. Саммерс Д., Уилки Ч., Даниэлс Ч. СПб.: Профессия, 2007. С. 218–220. ISBN 978-5-93913-153-7.
30. Manohar D.M., Chakraborty B.C., Begum S.S. Hardness–Elastic Modulus Relationship for Nitrile Rubber and Nitrile Rubber Polyvinyl Chloride Blends. In: Advances in Design and Thermal Systems. Select Proceedings of ETDMMT 2020. Ed. by Ganippa L., Karthikeyan R., Muralidharan V. Singapore: Singapore Pte Ltd. 2021. P. 301–314. DOI: 10.1007/978-981-33-6428–8_24.
31. Liu J., Pang X., Shi X., Xu J. Expandable Graphite in Polyethylene: The Effect of Modification, Particle Size and the Synergistic Effect with Ammonium Polyphosphate on Flame Retardancy, Thermal Stability and Mechanical Properties // Combustion Science and Technology. 2020. V. 192. P. 575–591. DOI: 10.1080/00102202.2019.1584797.
Review
For citations:
Galiguzov A.A., Serdan (jr.) A.A., Yashin N.V., Avdeev V.V. The influence of solid-phase fire retardants on the physical and mechanical properties of intumescent polymer materials based on plasticized polyvinyl chloride. Plasticheskie massy. 2025;(6):3-8. (In Russ.) https://doi.org/10.35164/0554-2901-2025-06-3-8
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