plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2023-7-8-31-36plasticnews-898Research ArticleСИНТЕЗ И ТЕХНОЛОГИЯSYNTHESIS AND TECHNOLOGYКонтролируемый синтез и свойства растворов сополимеров метакриловых эфиров и аммоний-содержащего метакриламидаControlled synthesis and solution properties of copolymers of methacrylic esters and ammonium-containing methacrylamideСимагинА. С.SimaginA. S.

г. Нижний Новгород

Nizhny Novgorod

alexandrsim11@gmail.comКазанцевО. А.KazantsevO. A.

г. Нижний Новгород

Nizhny Novgorod

КаморинД. М.KamorinD. M.

г. Нижний Новгород

Nizhny Novgorod

КаморинаН. С.KamorinaN. S.

г. Нижний Новгород

Nizhny Novgorod

КавтроваВ. Д.KavtrovaV. D.

г. Нижний Новгород

Nizhny Novgorod

Нижегородский государственный технический университет им. Р.Е. АлексееваРоссияNizhny Novgorod State Technical University n.a. R.E. AlekseevRussian Federation20230610202317-83136Copyright © Симагин А.С., Казанцев О.А., Каморин Д.М., Каморина Н.С., Кавтрова В.Д., 20232023Симагин А.С., Казанцев О.А., Каморин Д.М., Каморина Н.С., Кавтрова В.Д.Simagin A.S., Kazantsev O.A., Kamorin D.M., Kamorina N.S., Kavtrova V.D.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/898

Методом радикальной полимеризации с обратимой передачей цепи по механизму «присоединение-фрагментация» с высокими выходами и в контролируемом режиме получены сополимеры на основе олиго(этиленгликоль)метакрилата, додецилметакрилата и катионного мономера N-метакрилоиламинопропил-N,N-диметил-N-пропиламмоний бромида. Показано влияние состава полученных полимеров на растворимость в воде и органических растворителях, распределение в системе вода-октанол и межфазное натяжение на границе «вода-масло». Обнаружено наличие термочувствительных свойств для полимеров в воде, а также исследована их агрегация в водных средах.

Copolymers based on oligo(ethylene glycol) methacrylate, dodecyl methacrylate, and the cationic monomer N-methacryloylaminopropyl-N,N-dimethyl-N-propylammonium bromide have been obtained by reversible addition−fragmentation chain-transfer polymerization in high yields and in a controlled mode. The influence of the composition of the obtained polymers on the solubility in water and organic solvents, distribution in the water-octanol system, and interfacial tension at the water-oil interface is shown. The presence of thermoresponsive properties for polymers in water was found, and their aggregation in aqueous media was also studied.

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The authors declare that there are no conflicts of interest present.