plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2023-1-2-21-26plasticnews-831Research ArticleСИНТЕЗ И ТЕХНОЛОГИЯSYNTHESIS AND TECHNOLOGYСополимеризация N-[3-диалкиламинопропил]-метакриламидов с акриловыми амидами и эфирами в органических растворителяхCopolymerization of N-[3-dialkylaminopropyl]methacrylamides with acrylic amides and esters in organic solventsСадиковА. Ю.SadikovA. Yu.

г. Нижний Новгород

Nizhny Novgorod

КазанцевО. А.KazantsevO. A.

г. Нижний Новгород

Nizhny Novgorod

КаморинД. М.KamorinD. M.

г. Нижний Новгород

Nizhny Novgorod

d.kamorin@mail.ruСимагинА. С.SimaginA. S.

г. Нижний Новгород

Nizhny Novgorod

АрифуллинИ. Р.ArifullinI. R.

г. Нижний Новгород

Nizhny Novgorod

ОреховД. В.OrekhovD. V.

г. Нижний Новгород

Nizhny Novgorod

Нижегородский государственный технический университет им. Р.Е. АлексееваРоссияNizhny Novgorod State Technical University n.a. R.E. AlekseevRussian Federation20232403202311-22126Copyright © Садиков А.Ю., Казанцев О.А., Каморин Д.М., Симагин А.С., Арифуллин И.Р., Орехов Д.В., 20232023Садиков А.Ю., Казанцев О.А., Каморин Д.М., Симагин А.С., Арифуллин И.Р., Орехов Д.В.Sadikov A.Y., Kazantsev O.A., Kamorin D.M., Simagin A.S., Arifullin I.R., Orekhov D.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/831

Исследована радикальная сополимеризация N-[3-(диалкиламино)-пропил]метакриламидов с рядом (мет)акриловых амидов и эфиров в органических растворителях в широком интервале мольных соотношений. Методом Фэйнмана и Росса определены константы сополимеризации для пяти полимеризационных систем в 1,4-диоксане и толуоле. Обнаружено влияние растворителя на кинетику сополимеризации мономеров, выражающееся в изменении относительных активностей мономеров при варьировании полярности среды. Для полученных полимеров показано наличие термочувствительных свойств в водных растворах и влияние концентрации и состава сополимеров на их растворимость в воде.

The radical copolymerization of N-[3-(dialkylamino)-propyl]methacrylamides with a number of (meth)acrylic amides and esters in organic solvents over a wide range of molar ratios has been studied. Co-polymerisation constants for five polymerisation systems in 1,4-dioxane and toluene have been determined by the Feinman and Ross method. The influence of the solvent on the kinetics of the copolymerization of the studied monomers was found, which manifests itself in a change of the reactivity ratios of the monomers upon varying the polarity of the medium. For the obtained polymers, the presence of thermosensitive properties in aqueous solutions and the effect of the concentration and composition of copolymers on their solubility in water were shown.

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The authors declare that there are no conflicts of interest present.