plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2022-9-10-40-41plasticnews-791Research ArticleПЕРЕРАБОТКАRECYCLINGКомпозиционные материалы на основе фурановых аминопластов и наполнителя, полученных из возобновляемого сырьяComposite based on furan aminoplastics and filler obtained from renewable raw materialsТокаревД. В.TokarevD. V.

Новочеркасск

Novocherkassk

КатарияЯ. В.KatariaY. V.

Новочеркасск

Novocherkassk

КашпароваВ. П.KashparovaV. P.

Новочеркасск

Novocherkassk

КлушинВ. А.KlushinV. A.

Новочеркасск

Novocherkassk

victorxtf@yandex.ruСмирноваН. В.SmirnovaN. V.

Новочеркасск

Novocherkassk

Южно-Российский государственный политехнический университет (НПИ) имени М. И. ПлатоваРоссияPlatov South-Russian State Polytechnic UniversityRussian Federation20223011202209-104041Copyright © Токарев Д.В., Катария Я.В., Кашпарова В.П., Клушин В.А., Смирнова Н.В., 20222022Токарев Д.В., Катария Я.В., Кашпарова В.П., Клушин В.А., Смирнова Н.В.Tokarev D.V., Kataria Y.V., Kashparova V.P., Klushin V.A., Smirnova N.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/791

   Получены композиты на основе отходов производства 5-гидроксиметилфурфурола – «гуминов» и меламина или карбамида (в качестве сшивающего агента) с древесной мукой (в качестве наполнителя, 70 % масс.). Проведены исследования физико-механических свойств материалов с различным содержанием меламина или карбамида, которые показали, что композиты гумины: меламин (2,5: 1) и гумины:карбамид (2: 1) имеют предел прочности 150 и 165 МПа соответственно и не уступают по этому показателю аналогичным композитам на основе меламино- и карбамидо-формальдегидных смол.

   Composites based on waste products from the production of 5-hydroxymethylfurfural - "humins" and melamine or urea (as a cross-linking agent) with wood fl our (as a filler, 70 % by weight) were obtained. Studies of the physical and mechanical properties of materials with different contents of melamine or urea have been carried out, which have shown that the composites humins: melamine (2,5: 1) and humins:urea (2:1) have a tensile strength of 150 and 165 MPa, respectively, similar to composites based on melamine and urea-formaldehyde resins.

гуминымеламинкарбамидаминопластыкомпозитыфизико-механические свойстваhuminsmelamineureaamino plasticscompositesphysical and mechanical propertiesРабота выполнена на оборудовании Центра коллективного пользования «Нанотехнологии» Южно-Российского государственного политехнического университета (НПИ) имени М. И. Платова при финансовой поддержке Российского научного фонда (проект №21-13-00177)The work was carried out on the equipment of the Center for Collective Use "Nanotechnology" of the South Russian State Polytechnic University (NPI) named after M. I. Platov with the financial support of the Russian Science Foundation (project No. 21-13-00177)ReferencesHou Q. et al. Biorefi nery roadmap based on catalytic production and upgrading 5-hydroxymethylfurfural // Green Chemistry. 2021. V. 23, N.1. P. 119–231.Hou Q. et al. Biorefi nery roadmap based on catalytic production and upgrading 5-hydroxymethylfurfural // Green Chemistry. 2021. V. 23, N.1. P. 119–231.Zhao X. et al. Biomass-based chemical looping technologies: the good, the bad and the future // Energy & Environmental Science. 2017. V. 10, N. 9. P. 1885–1910.Zhao X. et al. Biomass-based chemical looping technologies: the good, the bad and the future // Energy & Environmental Science. 2017. V. 10, N. 9. P. 1885–1910.Klushin V. A. et al. Technological aspects of fructose conversion to high-purity 5-hydroxymethylfurfural, a versatile platform chemical // Russian Journal of Organic Chemistry. 2016. V. 52, N. 6. P. 767–771.Klushin V. A. et al. Technological aspects of fructose conversion to high-purity 5-hydroxymethylfurfural, a versatile platform chemical // Russian Journal of Organic Chemistry. 2016. V. 52, N. 6. P. 767–771.Клушин В. А. Оптимизация процесса дегидратации углеводов до 5-гидроксиметилфурфурола в двухфазной системе / В. А. Клушин [и др.] // Известия высших учебных заведений. Северо-Кавказский регион. Технические науки. – 2016. – № 4 (192). – С. 110–114.Клушин В. А. Оптимизация процесса дегидратации углеводов до 5-гидроксиметилфурфурола в двухфазной системе / В. А. Клушин [и др.] // Известия высших учебных заведений. Северо-Кавказский регион. Технические науки. – 2016. – № 4 (192). – С. 110–114.Kashparova V. P. et al. Furan monomers and polymers from renewable plant biomass // Russian Chemical Reviews. 2021. V. 90, N.6. P. 750.Kashparova V. P. et al. Furan monomers and polymers from renewable plant biomass // Russian Chemical Reviews. 2021. V. 90, N.6. P. 750.Kucherov F. A. et al. Chemical transformations of biomass-derived C6-furanic platform chemicals for sustainable energy research, materials science, and synthetic building blocks // ACS sustainable chemistry & engineering. 2018. V. 6, N. 7. P. 8064–8092.Kucherov F. A. et al. Chemical transformations of biomass-derived C6-furanic platform chemicals for sustainable energy research, materials science, and synthetic building blocks // ACS sustainable chemistry & engineering. 2018. V. 6, N. 7. P. 8064–8092.Galkin K. I., Ananikov V. P. Intermolecular Diels-Alder Cycloadditions of Furfural-Based Chemicals from Renewable Resources: A Focus on the Regio-and Diastereoselectivity in the Reaction with Alkenes // International Journal of Molecular Sciences. 2021. V. 22, N.21. P. 11856.Galkin K. I., Ananikov V. P. Intermolecular Diels-Alder Cycloadditions of Furfural-Based Chemicals from Renewable Resources: A Focus on the Regio-and Diastereoselectivity in the Reaction with Alkenes // International Journal of Molecular Sciences. 2021. V. 22, N.21. P. 11856.Tumolva T. et al. Evaluating the carbon storage potential of furan resin-based green composites // Proceedings of the 17th international conference on composite materials, Edinburgh, UK. 2009. P. 27–31.Tumolva T. et al. Evaluating the carbon storage potential of furan resin-based green composites // Proceedings of the 17th international conference on composite materials, Edinburgh, UK. 2009. P. 27–31.Ali A. et al. Hydrophobic treatment of natural fibers and their composites — A review //Journal of Industrial Textiles. 2018. V. 47, N. 8. P. 2153–2183.Ali A. et al. Hydrophobic treatment of natural fibers and their composites — A review //Journal of Industrial Textiles. 2018. V. 47, N. 8. P. 2153–2183.Mak K., Fam A. Fatigue Performance of Furfuryl Alcohol Resin Fiber-Reinforced Polymer for Structural Rehabilitation // Journal of Composites for Construction. 2020. V. 24, N.3. P. 04020012.Mak K., Fam A. Fatigue Performance of Furfuryl Alcohol Resin Fiber-Reinforced Polymer for Structural Rehabilitation // Journal of Composites for Construction. 2020. V. 24, N.3. P. 04020012.Shen H., Shan H., Liu L. Evolution process and controlled synthesis of humins with 5-hydroxymethylfurfural (HMF) as model molecule // Chem Sus Chem. 2020. V. 13. N 3. P. 513-519Shen H., Shan H., Liu L. Evolution process and controlled synthesis of humins with 5-hydroxymethylfurfural (HMF) as model molecule // Chem Sus Chem. 2020. V. 13. N 3. P. 513-519

The authors declare that there are no conflicts of interest present.