plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2022-3-4-30-33plasticnews-738Research ArticleСИНТЕЗ И ТЕХНОЛОГИЯSYNTHESIS AND TECHNOLOGYСинтез фосфазенметакрилатных олигомеров и их использование для модификации стоматологических композиционных материаловSynthesis of phosphazene methacrylate oligomers and their use for modification of dental composite materialsБиличенкоЮ. В.BILICHENKOYU. V.ШонВу СуанSONVU XUANТхуанФам ВанTHUANPHAM VANСиротинИ. С.SIROTINI. S.КиреевВ. В.KIREEVV. V.kireev.v.v@muctr.ruЧуевВ. П.CHUEVV. P.КлюкинБ. В.KLYUKINB. V.ПосоховаВ. Ф.POSOKHOVAV. F.Российский химико-технологический университет имени Д.И. МенделееваРоссияMendeleev University of Chemical Technology of RussiaRussian FederationАО ОЭЗ «ВЛАДМИВА»РоссияJSC «VLADMIVA» Experimental PlantRussian Federation20222405202203-43033Copyright © Биличенко Ю.В., Шон В., Тхуан Ф., Сиротин И.С., Киреев В.В., Чуев В.П., Клюкин Б.В., Посохова В.Ф., 20222022Биличенко Ю.В., Шон В., Тхуан Ф., Сиротин И.С., Киреев В.В., Чуев В.П., Клюкин Б.В., Посохова В.Ф.BILICHENKO Y.V., SON V., THUAN P., SIROTIN I.S., KIREEV V.V., CHUEV V.P., KLYUKIN B.V., POSOKHOVA V.F.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/738

Реакцией эпоксифосфазенов с метакриловой кислотой синтезированы метакрилатсодержащие фосфазеновые олигомеры (МФО), использованные для модификации стоматологических восстановительных материалов. Введение 10-15 мас.% МФО в базовый состав бис-метакрилатного связующего позволяет существенно повысить адгезию модифицированных отвержденных композиций к тканям зуба и металлам, а также улучшить водостойкость при сохранении требуемых ГОСТ-ом показателей прочности и других физико-химических характеристик.

The reaction of epoxyphosphazenes with methacrylic acid was used to synthesize methacrylate-containing phosphazene oligomers (MPO) used to modify dental restorative materials.

The introduction of 1015 wt.% MPO into the base bis-methacrylate binder composition can significantly increase the adhesion of modified cured compositions to tooth tissues and metals, as well as improve water resistance while maintaining the required strength indicators and other physicochemical characteristics required by GOST.

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The authors declare that there are no conflicts of interest present.