plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2021-9-10-12-17plasticnews-670Research ArticleСТРУКТУРА И СВОЙСТВАSTRUCTURE AND PROPERTIESФизико-химические свойства олиго(этиленгликоль)(мет)акрилатовPhysicochemical properties of oligo(ethylene glycol) (meth)acrylatesСавиноваМ. В.SavinovaM. V.

г. Нижний Новгород

Nizhny Novgorod

ШиршинК. В.ShirshinK. V.

г. Нижний Новгород

г. Дзержинск Нижегородской области

Nizhny Novgorod

Dzerzhinsk, Nizhny Novgorod region

shirshin@mail.ruБольшаковаЕ. А.Bol’shakovaE. A.

г. Нижний Новгород

Nizhny Novgorod

СимагинА. С.SimaginA. S.

г. Нижний Новгород

Nizhny Novgorod

КаморинД. М.KamorinD. M.

г. Нижний Новгород

Nizhny Novgorod

РябоваТ. А.RyabovaT. A.

г. Нижний Новгород

Nizhny Novgorod

КазанцевО. А.KazantsevO. A.

г. Нижний Новгород

Nizhny Novgorod

Нижегородский государственный технический университет им. Р.Е. АлексееваРоссияNizhny Novgorod State Technical University named by R.E. AlekseevRussian FederationНижегородский государственный технический университет им. Р.Е. Алексеева; АО «Научно-исследовательский институт химии и технологии полимеров имени академика В.А. Каргина с опытным заводом»РоссияNizhny Novgorod State Technical University named by R.E. Alekseev; V.A.Kargin Polymer Research InstituteRussian FederationНижегородский государственный технический университет им. Р.Е. Алексеева; Нижегородский государственный университет им. Н.И. ЛобачевскогоРоссияNizhny Novgorod State Technical University named by R.E. Alekseev; Lobachevsky State University of Nizhny NovgorodRussian Federation20211411202109-101217Copyright © Савинова М.В., Ширшин К.В., Большакова Е.А., Симагин А.С., Каморин Д.М., Рябова Т.А., Казанцев О.А., 20212021Савинова М.В., Ширшин К.В., Большакова Е.А., Симагин А.С., Каморин Д.М., Рябова Т.А., Казанцев О.А.Savinova M.V., Shirshin K.V., Bol’shakova E.A., Simagin A.S., Kamorin D.M., Ryabova T.A., Kazantsev O.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/670

В данном обзоре обобщены литературные данные по физико-химическим свойствам олиго(этиленгликоль)(мет) акрилатов. Рассмотрено влияние строения этих макромономеров на их растворимость, склонность к ассоциации в растворах, межфазную активность, реакционную способность в реакциях катализируемого кислотами и основаниями гидролиза, радикальной гомо- и сополимеризации.

This review summarizes the literature data on the physicochemical properties of oligo(ethylene glycol) (meth)acrylates. The influence of the structure of these macromonomers on their solubility, tendency to association in solutions, interfacial activity, reactivity in reactions of acid- and base-catalyzed hydrolysis, radical homo- and copolymerization is considered.

олиго(этиленгликоль)(мет)акрилатыамфифильные свойствагидрофильно-липофильный балансассоциациягидролизводные растворырадикальная полимеризацияoligo(ethyleneglycol) (meth)acrylatesamphiphilic propertieshydrophilic-lipophilic balanceassociationhydrolysisaqueous solutionsradical polymerizationИсследование амфифильных свойств АОЭГМ выполнено в рамках стипендии Президента Российской Федерации молодым ученым и аспирантам, осуществляющим перспективные научные исследования и разработки по приоритетным направлениям модернизации российской экономики (СП-954.2021.4), изучение закономерностей (со)полимеризации АОЭГМ – при финансовой поддержке РФФИ в рамках научного проекта № 20-33-90213\20.ReferencesIvanov, I.V. Amphiphilic multicomponent molecular brushes / I.V. Ivanov, T.K. Meleshko, A.V. Kashina, A.V. Yakimansky // Russian Chemical Reviews. – 2019. – Vol. 88, N 12. – P. 1248-1290.Ivanov, I.V. Amphiphilic multicomponent molecular brushes / I.V. Ivanov, T.K. Meleshko, A.V. Kashina, A.V. 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The authors declare that there are no conflicts of interest present.