plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2020-1-2-26-29plasticnews-468Research ArticleСЫРЬЁ И ВСПОМОГАТЕЛЬНЫЕ МАТЕРИАЛЫRAW AND AUXILIARY MATERIALSВлияние комплексного антипирена на физико-химические свойства ортофталевой ненасыщенной смолыEffect of complex flame retardant on physico-chemical properties of orthophthalic unsaturated resinЕвтушенкоЮ. М.YevtushenkoY. M.

Москва

Moscow

evt-yuri@mail.ruГригорьевЮ. А.GrigorievY. A.

Москва

Moscow

КучкинаИ. О.KuchkinaI. O.

Москва

Moscow

АфошинаЕ. В.AfoshinaE. V.

Московская обл, Сергиево-Посадский р-н, г Хотьково

Moscow region

КрушевскийГ. А.KrushevskyG. A.

Московская обл, Сергиево-Посадский р-н, г Хотьково

Moscow region

Федеральное государственное бюджетное учреждение науки Институт синтетических полимерных материалов им. Н.С. Ениколопова Российской академии наук (ИСПМ РАН)РоссияN.S. Enikolopov Institute of Synthetic Polymeric Materials Russian Academy of Sciences (ISPM RAS)Russian FederationПубличное акционерное общество «Электроизолит»РоссияElectroizolit PJSCRussian Federation20201903202001-22629Copyright © Евтушенко Ю.М., Григорьев Ю.А., Кучкина И.О., Афошина Е.В., Крушевский Г.А., 20202020Евтушенко Ю.М., Григорьев Ю.А., Кучкина И.О., Афошина Е.В., Крушевский Г.А.Yevtushenko Y.M., Grigoriev Y.A., Kuchkina I.O., Afoshina E.V., Krushevsky G.A.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/468

В работе представлен краткий обзор результатов исследований снижения горючести композиционных материалов на основе ненасыщенных полиэфирных смол. Разработана и исследована трудногорючая ортофталевая ненасыщенная смола на основе комплексного антипирена. Показано, что категория стойкости к горению смолы достигается при 15–20%-ном наполнении комплексным антипиреном на основе полифосфата аммония, меламина и пентаэритрита. Оценены кинетика отверждения и физико-механические свойства композиционного материала.

A brief review of the results of studies on reducing the combustibility of composite materials based on unsaturated polyester resins is presented. A flame retardant orthophthalic unsaturated resin based on a complex flame retardant was developed and studied. It is shown that the category for resistance to burning of the resin is achieved with 15–20% filling of the complex flame retardant based on ammonium polyphosphate, melamine and pentaerythritol. The kinetics of curing and physical and mechanical properties of the composite material are evaluated.

ненасыщенная полиэфирная смолаантипиренгорючестьполифосфат аммониямеламинпентаэритритunsaturated polyester resinflame retardantflammabilityammonium polyphosphatemelaminepentaerythritolReferencesE.D. Weil, S.V. Levchik. Review Commercial Flame Retardancy of Unsaturated Polyester and Vinyl Resins: Review. J. Fire Sci. 2004. V. 22. No. 4. P. 293-303.E.D. Weil, S.V. Levchik. Review Commercial Flame Retardancy of Unsaturated Polyester and Vinyl Resins: Review. J. Fire Sci. 2004. V. 22. No. 4. P. 293-303.E. Kicko-Walczak, G. Rymarz. Flame-Retardant Unsaturated Polyester Resins: An Overview of Past and Recent Developments. 10th International Conference on Composite Science and Technology ICCST/10 A.L. Araújo, J.R. Correia, C.M. Mota Soares, et al. (Editors) © IDMEC 2015. December 20th 2017. DOI: 10.5772/intechopen.72536.E. Kicko-Walczak, G. Rymarz. Flame-Retardant Unsaturated Polyester Resins: An Overview of Past and Recent Developments. 10th International Conference on Composite Science and Technology ICCST/10 A.L. Araújo, J.R. Correia, C.M. Mota Soares, et al. (Editors) © IDMEC 2015. December 20th 2017. DOI: 10.5772/intechopen.72536.M. Rakotomalala, S. Wagner, M. Doring. Recent developments in halogen free flame retardant for epoxy resins for electrical and electronic applications. Journal of Materials. 2010. V.3. P. 4300-4327.M. Rakotomalala, S. Wagner, M. Doring. Recent developments in halogen free flame retardant for epoxy resins for electrical and electronic applications. Journal of Materials. 2010. V.3. P. 4300-4327.H. Tang, X. Zhou, X. Liu. Effect of Magnesium Hydroxide on the Flame Retardant Properties of Unsaturated Polyester Resin. Procedia Engineering. 2013. V. 52. P. 336341.H. Tang, X. Zhou, X. Liu. Effect of Magnesium Hydroxide on the Flame Retardant Properties of Unsaturated Polyester Resin. Procedia Engineering. 2013. V. 52. P. 336341.J. Klemeš, P. Y. Liew, W. S. Ho, J. S. Lim. Synthesis and Characterisation of Unsaturated Polyester Resin /Aluminium Hydroxide/Magnesium Hydroxide Fire Retardant. Composite Chem. Eng. Transactions. 2017. V. 56. A publication of the Italian Association of Chemical Engine resin.J. Klemeš, P. Y. Liew, W. S. Ho, J. S. Lim. Synthesis and Characterisation of Unsaturated Polyester Resin /Aluminium Hydroxide/Magnesium Hydroxide Fire Retardant. Composite Chem. Eng. Transactions. 2017. V. 56. A publication of the Italian Association of Chemical Engine resin.T.D. Hapuarachchi1, T. Peijs. Aluminium trihydroxide in combination with ammoniumpolyphosphate as flame retardants for unsaturated polyester resin. eXPRESS Polymer Letters. 2009. V. 3. No.11. P. 743-751.T.D. Hapuarachchi1, T. Peijs. Aluminium trihydroxide in combination with ammoniumpolyphosphate as flame retardants for unsaturated polyester resin. eXPRESS Polymer Letters. 2009. V. 3. No.11. P. 743-751.S. Nazare, B. K. Kandola and A. R. Horrocks. Flame-retardant unsaturated polyester resin incorporating nanoclays. Adv. Technol. 2006. V. 17. P. 294-303.S. Nazare, B. K. Kandola and A. R. Horrocks. Flame-retardant unsaturated polyester resin incorporating nanoclays. Adv. Technol. 2006. V. 17. P. 294-303.C. M.C. Pereira, A. T. Marques. Kinetic studies of flame-retardant unsaturated polyester nanocomposites: the effect of aluminum hydroxide (ATH), ammonium polyphosphate (APP) and nanoclays. 16-th International Conference on Composite Materials. Kyoto. Japan. 2007.C. M.C. Pereira, A. T. Marques. Kinetic studies of flame-retardant unsaturated polyester nanocomposites: the effect of aluminum hydroxide (ATH), ammonium polyphosphate (APP) and nanoclays. 16-th International Conference on Composite Materials. Kyoto. Japan. 2007.P. Penczek, R. Ostrysz, D. Krassowski. Expandable Graphite as a Fire Retardant in Unsaturated Polyester Resins. Paper presented at Fire Retardants 2000. London, England, 2000. Updated November 2012.P. Penczek, R. Ostrysz, D. Krassowski. Expandable Graphite as a Fire Retardant in Unsaturated Polyester Resins. Paper presented at Fire Retardants 2000. London, England, 2000. Updated November 2012.E. Kandare, C. Chukwudolue, K. Baljinder. The use of fire-retardant intumescent mats for fire and heat protection of glass fibre-reinforced polyester composites: Thermal barrier properties. Fire and materials. 2010. V. 34. No. 1. P. 21-38.E. Kandare, C. Chukwudolue, K. Baljinder. The use of fire-retardant intumescent mats for fire and heat protection of glass fibre-reinforced polyester composites: Thermal barrier properties. Fire and materials. 2010. V. 34. No. 1. P. 21-38.N. Maheshwari1, S. Thakur, P. Neogi, S. Neogi1. UV resistance and fire retardant property enhancementof unsaturated polyester composite. Polymer Bulletin. 2015. V. 72. No. 6. P. 1433-1447.N. Maheshwari1, S. Thakur, P. Neogi, S. Neogi1. UV resistance and fire retardant property enhancementof unsaturated polyester composite. Polymer Bulletin. 2015. V. 72. No. 6. P. 1433-1447.M. Jiang, Y. Yu, Z. Chen. Environmentally Friendly Flame Retardant Systems for Unsaturated Polyester Resin. 2nd International Symposium on Resource Exploration and Environmental Science IOP Publishing IOP Conf. Series: Earth and Environmental Science 170. 2018. 032116. doi:10.1088/1755-1315/170/3/032116.M. Jiang, Y. Yu, Z. Chen. Environmentally Friendly Flame Retardant Systems for Unsaturated Polyester Resin. 2nd International Symposium on Resource Exploration and Environmental Science IOP Publishing IOP Conf. Series: Earth and Environmental Science 170. 2018. 032116. doi:10.1088/1755-1315/170/3/032116.Z. Chen, M. Jiang, Q. Zhang, Y. Yu, G. Sun, J. Jiang. Synergistic Effect of Combined Dimethyl Methyiphosphonate with Aluminum Hydroxide or Ammonium Polyphosphate Retardants Systems on the Flame Retardancy and Thermal Properties of Unsaturated Polyester Resin. International Journal of Polymer Analysis and Characterization. 2017. V. 22. No. 6. P. 509-518.Z. Chen, M. Jiang, Q. Zhang, Y. Yu, G. Sun, J. Jiang. Synergistic Effect of Combined Dimethyl Methyiphosphonate with Aluminum Hydroxide or Ammonium Polyphosphate Retardants Systems on the Flame Retardancy and Thermal Properties of Unsaturated Polyester Resin. International Journal of Polymer Analysis and Characterization. 2017. V. 22. No. 6. P. 509-518.M. Ribeiro, S. Sousa, P.J.R. Oliveira, C.M.C. Riveira. Fire retardancy enhancement of unsaturated polyester polymer resin filled with nano and microparticulate oxide additives. IOP Conf. Ser.: Mater. Sci. Eng. 2014. V. 58. 012020. doi:10.1088/1757-899X/58/1/0120202.M. Ribeiro, S. Sousa, P.J.R. Oliveira, C.M.C. Riveira. Fire retardancy enhancement of unsaturated polyester polymer resin filled with nano and microparticulate oxide additives. IOP Conf. Ser.: Mater. Sci. Eng. 2014. V. 58. 012020. doi:10.1088/1757-899X/58/1/0120202.B.K. Kandola, J.R. Ebdon, K.P. Chowdhury. Flame Retardance and Physical Properties of Novel Cured Blends of Unsaturated Polyester and Furan Resins. Polymers. 2015. V. 7. P. 298. doi:10.3390/polym7020298.B.K. Kandola, J.R. Ebdon, K.P. Chowdhury. Flame Retardance and Physical Properties of Novel Cured Blends of Unsaturated Polyester and Furan Resins. Polymers. 2015. V. 7. P. 298. doi:10.3390/polym7020298.Z. Bai, L. Song, Y. Hu, R. K. K. Yuen. Preparation, Flame Retardancy, and Thermal Degradation of Unsaturated Polyester Resin Modified with a Novel Phosphorus Containing Acrylate. Ind. Eng. Chem. Res. 2013. V. 52. P. 12855-12864.Z. Bai, L. Song, Y. Hu, R. K. K. Yuen. Preparation, Flame Retardancy, and Thermal Degradation of Unsaturated Polyester Resin Modified with a Novel Phosphorus Containing Acrylate. Ind. Eng. Chem. Res. 2013. V. 52. P. 12855-12864.V. Rusnák1, S. Rusnáková, L. Fojtl. Flame resistance and mechanical properties of composites based on new advanced resin systemer 4/12. Materials and technology. 2015. V.49. No. 5. P. 821-1824.V. Rusnák1, S. Rusnáková, L. Fojtl. Flame resistance and mechanical properties of composites based on new advanced resin systemer 4/12. Materials and technology. 2015. V.49. No. 5. P. 821-1824.Yu. M. Evtushenko, Yu. A. Grigoriev, T.A. Rudakova, A.N. Ozerin. Effect of aluminum hydroxide on the fireproofing properties of ammonium polyphosphate-pentaerythritol-based intumescent coating. J. Coat. Techn. Res. 2019. V. 16. No. 5. P. 1389-1398.Yu. M. Evtushenko, Yu. A. Grigoriev, T.A. Rudakova, A.N. Ozerin. Effect of aluminum hydroxide on the fireproofing properties of ammonium polyphosphate-pentaerythritol-based intumescent coating. J. Coat. Techn. Res. 2019. V. 16. No. 5. P. 1389-1398.

The authors declare that there are no conflicts of interest present.