plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2019-9-10-34-38plasticnews-420Research ArticleСИНТЕЗ И ТЕХНОЛОГИЯSYNTHESIS AND TECHNOLOGYДисперсионная полимеризация н-бутилакрилата под действием сополимеров акриловой кислоты и N-изопропилакриламидаDispersion polymerization of n-butylacrylate under the action of acrylic acid and N-isopropylacrylamide copolymersСерхачеваН. С.SerkhachevaN. S.

Москва

Moscow

natalia-serkhacheva@yandex.ruЧерниковаЕ. В.ChernikovaE. V.

Москва

Moscow

ПрокоповН. И.ProkopovN. I.

Москва

Moscow

БалашовМ. С.BalashovM. S.

Москва

Moscow

ОгайВ. В. OgayV. V.

Москва

Moscow

ТомсР. В.TomsR. V.

Москва

Moscow

МИРЭА – Российский технологический университет, институт тонких химических технологий имени М.В. ЛомоносоваРоссияMIREA – Russian Technological UniversityRussian FederationМосковский государственный университет имени М.В. ЛомоносоваРоссияLomonosov Moscow State UniversityRussian Federation20190211201909-103438Copyright © Серхачева Н.С., Черникова Е.В., Прокопов Н.И., Балашов М.С., Огай В.В., Томс Р.В., 20192019Серхачева Н.С., Черникова Е.В., Прокопов Н.И., Балашов М.С., Огай В.В., Томс Р.В.Serkhacheva N.S., Chernikova E.V., Prokopov N.I., Balashov M.S., Ogay V.V., Toms R.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/420

Исследованы закономерности дисперсионной радикальной полимеризации н-бутилакрилата в водно-спиртовой среде под действием полимерных тритиокарбонатов на основе сополимеров акриловой кислоты и N-изопропилакриламида. Найдены условия образования блок-сополимера с контролируемой молекулярной массой и высоким выходом. Синтезированы устойчивые суспензии блок-сополимеров с унимодальным распределением частиц по размерам.

The regularities of dispersion radical polymerization of n-butylacrylate in water-alcohol medium under the action of polymer tritiocarbonates based on copolymers of acrylic acid and N-isopropylacrylamide have been investigated. The conditions for the formation of a block copolymer with controlled molecular weight and high yield have been found. The conditions of formation of stable suspensions of block copolymers with unimodal particle size distribution have been determined.

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The authors declare that there are no conflicts of interest present.