plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2019-7-8-38-41plasticnews-399Research Article70 ЛЕТ НИИ ПОЛИМЕРОВ ИМЕНИ АКАДЕМИКА В.А. КАРГИНААмфифильные свойства алкоксиолигоэтиленгликольметакрилатов и сополимеров на их основеAmphiphilic properties of alkoxyoligoethyleneglycol methacrylates and copolymers based on themОреховД. В.OrekhovD. V.

г. Нижний Новгород

Nizhny Novgorod

ШиршинК. В.ShirshinK. V.

г. Нижний Новгород;

г. Дзержинск Нижегородской области

Nizhny Novgorod;

Dzerzhinsk, Nizhny Novgorod Region

shirshin@nicp.ruСавиноваМ. В.SavinovaM. V.

г. Нижний Новгород

Nizhny Novgorod

КазанцевО. А.KazantsevO. A.

г. Нижний Новгород

Nizhny Novgorod

КаморинД. М.KamorinD. M.

г. Нижний Новгород

Nizhny Novgorod

ЛогутовВ. И.LogutovV. I.

г. Нижний Новгород

Nizhny Novgorod

Нижегородский государственный технический университет им. Р.Е. АлексееваРоссияR.E. Alekseev Nizhny Novgorod State Technical UniversityRussian FederationНижегородский государственный технический университет им. Р.Е. Алексеева; АО «Научно-исследовательский институт химии и технологии полимеров имени академика В.А. Каргина с опытным заводом»РоссияR.E. Alekseev Nizhny Novgorod State Technical University; JSC V.A. Kargin Scientifi c Research Institute of Chemistry and Technology of Polymers with a pilot plantRussian FederationНижегородский государственный технический университет им. Р.Е. Алексеева; Нижегородский государственный университет им. Н.И. ЛобачевскогоРоссияR.E. Alekseev Nizhny Novgorod State Technical UniversityRussian FederationНижегородский государственный университет им. Н.И. ЛобачевскогоРоссияN.I. Lobachevsky Nizhny Novgorod State UniversityRussian Federation20191109201907-83841Copyright © Орехов Д.В., Ширшин К.В., Савинова М.В., Казанцев О.А., Каморин Д.М., Логутов В.И., 20192019Орехов Д.В., Ширшин К.В., Савинова М.В., Казанцев О.А., Каморин Д.М., Логутов В.И.Orekhov D.V., Shirshin K.V., Savinova M.V., Kazantsev O.A., Kamorin D.M., Logutov V.I.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/399

На основе данных по распределению алкоксиолиго(этиленгликоль)метакрилатов в системе вода-гексан определены значения ГЛБ макромономеров. Показана хорошая корреляция между температурами фазовых переходов сополимеров алкоксиолиго(этиленгликоль)метакрилатов в водных растворах и расчетными значениями ГЛБ исходных макромономеров.

Based on the data on the distribution of alkoxyoligo(ethyleneglycol) methacrylates in the water-hexane system, the HLB values of the macromonomers are determined. A good correlation between the temperatures of phase transitions of copolymers of alkoxyoligo(ethyleneglycol) methacrylates in aqueous solutions and calculated HLB values of the original macromonomers was shown.

алкоксиолиго(этиленгликоль)метакрилатыамфифильные свойстваГЛБрадикальная сополимеризациясополимерыводные растворынизшая критическая температура растворениякорреляцияalkoxyoligo(ethyleneglycol) methacrylatesamphiphilic propertiesHLBradical copolymerizationcopolymersaqueous solutionslower critical solution temperaturecorrelationРабота по исследованию амфифильных свойств алкоксиолиго- (этиленгликоль)метакрилатов выполнена при финансовой поддержке Российского фонда фундаментальных исследований в рамках научного проекта № 18-33-00989 мол_а. Работа по синтезу и исследованию термочувствительных сополимеров олиго(этиленгликоль)метакрилатов выполнена при финансовой поддержке Российского научного фонда в рамках научного проекта № 18-73- 00297.ReferencesSakai E., Ishida A., Ohta A. New Trends in the Development of Chemical Admixtures in Japan // J. Adv. Concr. Technol. ‒ 2006. ‒ V. 4, N 2. ‒ P. 211-223.Sakai E., Ishida A., Ohta A. 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The authors declare that there are no conflicts of interest present.