<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">plasticnews</journal-id><journal-title-group><journal-title xml:lang="ru">Пластические массы</journal-title><trans-title-group xml:lang="en"><trans-title>Plasticheskie massy</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0554-2901</issn><publisher><publisher-name>PLASTMASSY Publishing House (Moscow)</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.35164/0554-2901-2025-06-45-48</article-id><article-id custom-type="elpub" pub-id-type="custom">plasticnews-1198</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>СИНТЕЗ И ТЕХНОЛОГИЯ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>SYNTHESIS AND TECHNOLOGY</subject></subj-group></article-categories><title-group><article-title>Влияние силанизации диоксида титана на свойства полимерных концентратов</article-title><trans-title-group xml:lang="en"><trans-title>The effect of silanization of titanium dioxide on the properties of polymer masterbatches</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Капличенко</surname><given-names>Д. А.</given-names></name><name name-style="western" xml:lang="en"><surname>Kaplichenko</surname><given-names>D. A.</given-names></name></name-alternatives><email xlink:type="simple">kaplichenkoda@gmail.com</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Де Векки</surname><given-names>Д. А.</given-names></name><name name-style="western" xml:lang="en"><surname>De Vekki</surname><given-names>D. A.</given-names></name></name-alternatives><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Санкт-Петербургский государственный технологический институт (технический университет)</institution><country>Россия</country></aff><aff xml:lang="en"><institution>St. Petersburg State Institute of Technology (Technical University)</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>25</day><month>12</month><year>2025</year></pub-date><volume>0</volume><issue>6</issue><fpage>45</fpage><lpage>48</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Капличенко Д.А., Де Векки Д.А., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Капличенко Д.А., Де Векки Д.А.</copyright-holder><copyright-holder xml:lang="en">Kaplichenko D.A., De Vekki D.A.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.plastics-news.ru/jour/article/view/1198">https://www.plastics-news.ru/jour/article/view/1198</self-uri><abstract><p>Исследованы модификация поверхности диоксида титана октилтриэтоксисиланом и олигомерным короткоцепочечным алкилфункциональным силаном Dynasylan 9896 и влияние силанизации на свойства белых полимерных концентратов. Показаны возрастание разбеливающей способности и гидрофобных свойств поверхности TiO2 при силанизации, снижение количества агломератов и улучшение ПТР полимерных концентратов на основе модифицированного TiO2.</p></abstract><trans-abstract xml:lang="en"><p>The modification of titanium dioxide surface with octyltriethoxysilane and oligomeric short-chain alkylfunctional silane Dynasylan 9896 was studied. The eff ect of silanization on the properties of white masterbatches was investigated. An increase in the bleachig power and hydrophobic properties of the TiO2 surface by silanization, a decrease in the amount of agglomerates and an improvement in the MFI of masterbatches based on modified TiO2 were shown.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>диоксид титана</kwd><kwd>силан</kwd><kwd>полимерный концентрат</kwd><kwd>силанизация</kwd><kwd>модификация поверхности</kwd></kwd-group><kwd-group xml:lang="en"><kwd>titanium dioxide</kwd><kwd>silane</kwd><kwd>masterbatche</kwd><kwd>silanization</kwd><kwd>surface</kwd><kwd>modification</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Winkler J. Titanium Dioxide: Production, Properties and Effective Usage. Hanover: Vinecentz, 2013. 150 p. ISBN: 3866308124.</mixed-citation><mixed-citation xml:lang="en">Winkler J. Titanium Dioxide: Production, Properties and Effective Usage. Hanover: Vinecentz, 2013. 150 p. ISBN: 3866308124.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Brząkalski D., Przekop R.E., Frydrych M., Pakuła D., Dobrosielska M., Sztorch B., Marciniec B. Where ppm Quantities of Silsesqui oxanes Make a Difference−Silanes and Cage Siloxanes as TiO2 Dispersants and Stabilizers for Pigmented Epoxy Resins // Mater. 2022. Vol. 15, N2. P. 494. DOI: 10.3390/ma15020494.</mixed-citation><mixed-citation xml:lang="en">Brząkalski D., Przekop R.E., Frydrych M., Pakuła D., Dobrosielska M., Sztorch B., Marciniec B. Where ppm Quantities of Silsesqui oxanes Make a Difference−Silanes and Cage Siloxanes as TiO2 Dispersants and Stabilizers for Pigmented Epoxy Resins // Mater. 2022. Vol. 15, N2. P. 494. DOI: 10.3390/ma15020494.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Sabzi M., Mirabedin S. M., Zohuriaan-Mehr J., Atai M. Surface modification of TiO2 nano-particles with silane coupling agent and investigation of its effect on the properties of polyurethane compos ite coating // Prog. Org. Coat. 2009. Vol. 65, N2. P. 222–228. DOI: 10.1016/j.porgcoat.2008.11.006.</mixed-citation><mixed-citation xml:lang="en">Sabzi M., Mirabedin S. M., Zohuriaan-Mehr J., Atai M. Surface modification of TiO2 nano-particles with silane coupling agent and investigation of its effect on the properties of polyurethane compos ite coating // Prog. Org. Coat. 2009. Vol. 65, N2. P. 222–228. DOI: 10.1016/j.porgcoat.2008.11.006.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Nguyen T.-C., Nguyen T.-D., Vu D.-T., Dinh D.-P., Nguyen A.-H., Ly T.-N., Dao P.-H., Nguyen T.-L., Bach L.-G., Thai H. Modification of Titanium Dioxide Nanoparticles with 3-(Trimethoxysilyl)propyl Methacrylate Silane Coupling Agent // J. Chem. 2020. Article ID 1381407. 10 p. DOI: 10.1155/2020/1381407.</mixed-citation><mixed-citation xml:lang="en">Nguyen T.-C., Nguyen T.-D., Vu D.-T., Dinh D.-P., Nguyen A.-H., Ly T.-N., Dao P.-H., Nguyen T.-L., Bach L.-G., Thai H. Modification of Titanium Dioxide Nanoparticles with 3-(Trimethoxysilyl)propyl Methacrylate Silane Coupling Agent // J. Chem. 2020. Article ID 1381407. 10 p. DOI: 10.1155/2020/1381407.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Zhao J., Milanova M., Warmoeskerken M.M.C.G., Dutschk V. Surface modification of TiO2 nanoparticles with silane coupling agents, Coll. Surf. A: Physicochem. Eng. Aspects. 2012. Vol. 413. P. 273–279. DOI: 10.1016/j.colsurfa.2011.11.033.</mixed-citation><mixed-citation xml:lang="en">Zhao J., Milanova M., Warmoeskerken M.M.C.G., Dutschk V. Surface modification of TiO2 nanoparticles with silane coupling agents, Coll. Surf. A: Physicochem. Eng. Aspects. 2012. Vol. 413. P. 273–279. DOI: 10.1016/j.colsurfa.2011.11.033.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Zhang W., Guo H., Sun H., Zeng R.-C. Photogenerated cathodic protection and invalidation of silane/TiO2 hybrid coatings // J. Coat. Technol. Res. 2017. Vol. 14, N2. P. 417–424. DOI:10.1007/s11998-016-9859-4.</mixed-citation><mixed-citation xml:lang="en">Zhang W., Guo H., Sun H., Zeng R.-C. Photogenerated cathodic protection and invalidation of silane/TiO2 hybrid coatings // J. Coat. Technol. Res. 2017. Vol. 14, N2. P. 417–424. DOI:10.1007/s11998-016-9859-4.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Цвайфель Х., Маер Р.Д., Шиллер М. Добавки к полимерам. Справочник. СПб: Профессия, 2010. 1088 с. ISBN: 978-5-91884 008-5.</mixed-citation><mixed-citation xml:lang="en">Цвайфель Х., Маер Р.Д., Шиллер М. Добавки к полимерам. Справочник. СПб: Профессия, 2010. 1088 с. ISBN: 978-5-91884 008-5.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Tolinski M. Additives for Polyolefins, Getting the Most out of Polypropylene, Polyethylene and TPO. Amsterdam: William Andrew. 2015. 240 p. ISBN: 978-0-323-35884-2.</mixed-citation><mixed-citation xml:lang="en">Tolinski M. Additives for Polyolefins, Getting the Most out of Polypropylene, Polyethylene and TPO. Amsterdam: William Andrew. 2015. 240 p. ISBN: 978-0-323-35884-2.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Elshereksi N.W., Ghazali M., Muchtar A., Azhari C.H. Review of titanate coupling agents and their application for dental composite fabrication // Dent. Mater. J. 2017. Vol. 36, N5. P. 539–552. DOI: 10.4012/dmj.2016-014.</mixed-citation><mixed-citation xml:lang="en">Elshereksi N.W., Ghazali M., Muchtar A., Azhari C.H. Review of titanate coupling agents and their application for dental composite fabrication // Dent. Mater. J. 2017. Vol. 36, N5. P. 539–552. DOI: 10.4012/dmj.2016-014.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Witucki G.L. A Silane Primer: Chemistry and Applications of AIkoxy Silanes // J. Coat. Technol. 1993. Vol. 65, N822. P. 57–60.</mixed-citation><mixed-citation xml:lang="en">Witucki G.L. A Silane Primer: Chemistry and Applications of AIkoxy Silanes // J. Coat. Technol. 1993. Vol. 65, N822. P. 57–60.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Monte S.J. Neoalkoxy Titanate and Zirconate Coupling Agent Addi tives in Thermoplastics // Polym. Polym. Comp. 2002. Vol. 10, N2. P. 121–172. DOI: 10.1177/096739110201000202.</mixed-citation><mixed-citation xml:lang="en">Monte S.J. Neoalkoxy Titanate and Zirconate Coupling Agent Addi tives in Thermoplastics // Polym. Polym. Comp. 2002. Vol. 10, N2. P. 121–172. DOI: 10.1177/096739110201000202.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Pape G.P., Plueddeman E.P., Methods for improving the Performance of Silane Coupling Agents // J. Adhes. Sci. Technol. 2012. Vol. 5, N10. P. 831–842. DOI: 10.1163/156856191X00242.</mixed-citation><mixed-citation xml:lang="en">Pape G.P., Plueddeman E.P., Methods for improving the Performance of Silane Coupling Agents // J. Adhes. Sci. Technol. 2012. Vol. 5, N10. P. 831–842. DOI: 10.1163/156856191X00242.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Ngouangna E.N., Jaafar M.Z., Norddin M., Agi A., Oseh J.O., Mamah S. Surface modification of nanoparticles to improve oil recovery Mechanisms: A critical review of the methods, influencing Parameters, advances and prospects // J. Mol. Liq. 2022. Vol. 360. P. 119502. DOI: 10.1016/j.molliq.2022.119502.</mixed-citation><mixed-citation xml:lang="en">Ngouangna E.N., Jaafar M.Z., Norddin M., Agi A., Oseh J.O., Mamah S. Surface modification of nanoparticles to improve oil recovery Mechanisms: A critical review of the methods, influencing Parameters, advances and prospects // J. Mol. Liq. 2022. Vol. 360. P. 119502. DOI: 10.1016/j.molliq.2022.119502.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Wang L., Jiang X., Wang C., Huang Y., Meng Y., Shao J. Titanium dioxide grafted with silane coupling agents and its use in blue light curing ink // Coloration Technol. 2020. Vol. 136, N1. P. 15–22. DOI: 10.1111/cote.12434.</mixed-citation><mixed-citation xml:lang="en">Wang L., Jiang X., Wang C., Huang Y., Meng Y., Shao J. Titanium dioxide grafted with silane coupling agents and its use in blue light curing ink // Coloration Technol. 2020. Vol. 136, N1. P. 15–22. DOI: 10.1111/cote.12434.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Chen P., Wei B., Zhu X., Gao D., Cheng J., Liu Y., Fabrication and characterization of highly hydrophobic rutile TiO2-based coat ings for self-cleaning // Ceramics International. 2019. Vol. 45, N5. P. 6111–6118. DOI: 10.1016/j.ceramint.2018.12.085.</mixed-citation><mixed-citation xml:lang="en">Chen P., Wei B., Zhu X., Gao D., Cheng J., Liu Y., Fabrication and characterization of highly hydrophobic rutile TiO2-based coat ings for self-cleaning // Ceramics International. 2019. Vol. 45, N5. P. 6111–6118. DOI: 10.1016/j.ceramint.2018.12.085.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Pat. US 4601503. Int. Cl. C09C 1/36. Silane Treatment of Titanium Dioxide Pigment: appl. N 727673: reg. 29.09.1976: publ. 06.12.1977 / Berger S.E., Salensky G.A. 11 p.</mixed-citation><mixed-citation xml:lang="en">Pat. US 4601503. Int. Cl. C09C 1/36. Silane Treatment of Titanium Dioxide Pigment: appl. N 727673: reg. 29.09.1976: publ. 06.12.1977 / Berger S.E., Salensky G.A. 11 p.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Kulal A.B., Kasabe M.M., Jadhav P., Dongare M.K., Umbarkar S.B. Hydrophobic WO3/SiO2 catalyst for the nitration of aromatics in liquid phase // Appl. Catal. A: Gen. 2019. Vol. 574. P. 105–113. DOI: 10.1016/j.apcata.2019.02.002.</mixed-citation><mixed-citation xml:lang="en">Kulal A.B., Kasabe M.M., Jadhav P., Dongare M.K., Umbarkar S.B. Hydrophobic WO3/SiO2 catalyst for the nitration of aromatics in liquid phase // Appl. Catal. A: Gen. 2019. Vol. 574. P. 105–113. DOI: 10.1016/j.apcata.2019.02.002.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
