plasticnewsПластические массыPlasticheskie massy0554-2901PLASTMASSY Publishing House (Moscow)10.35164/0554-2901-2025-06-21-23plasticnews-1192Research ArticleСТРУКТУРА И СВОЙСТВАSTRUCTURE AND PROPERTIESПолиуретановые гель-электролиты на основе фосфорорганических разветвленных иономерных полиоловPolyurethane gel electrolytes based on organophosphorus branched ionomer polyolsДавлетбаевР. С.DavletbaevR. S.darus@rambler.ruНизамовА. А.NizamovA. A.ЯрмоленкоО. В.YarmolenkoO. V.СазоновО. О.SazonovO. O.ДавлетбаеваИ. М.DavletbaevaI. M.Казанский государственный энергетический университетРоссияKazan State Power Engineering UniversityRussian FederationФедеральный исследовательский центр проблем химической физики и медицинской химии РАНРоссияFederal Research Center for Chemical Physics and Medical Chemistry of the Russian Academy of SciencesRussian FederationКазанский национальный исследовательский технологический университетРоссияKazan National Research Technological UniversityRussian Federation202525122025062123Copyright © Давлетбаев Р.С., Низамов А.А., Ярмоленко О.В., Сазонов О.О., Давлетбаева И.М., 20252025Давлетбаев Р.С., Низамов А.А., Ярмоленко О.В., Сазонов О.О., Давлетбаева И.М.Davletbaev R.S., Nizamov A.A., Yarmolenko O.V., Sazonov O.O., Davletbaeva I.M.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.plastics-news.ru/jour/article/view/1192

Работа посвящена исследованию ионной проводимости и особенностей построения надмолекулярной структуры полиуретановых гель-электролитов (ПГЭ), получаемых с использованием фосфорорганических разветвленных иономерных полиолов (ФИП–ППО), модифицированных янтарным ангидридом (ЯА). Показано, что использование ЯА при синтезе ФИП–ППО привело к повышению ионной проводимости ПГЭ в четыре раза. Установлено, что объединение фосфат-анионов в кластеры и введение карбоксилат-анионов в структуру кластеров приводит к изменению упаковки как ФИП–ППО, так и получаемых с их использованием полиуретанов.

Ionic conductivity and features of the construction of the supramolecular structure of polyurethane gel electrolytes (PGE) obtained using organophosphorus branched ionomer polyols (OPIP) modified with succinic anhydride (SA) have been studied. It is shown that the use of SA in the synthesis of OPIP led to a fourfold increase in the ionic conductivity of PGE. It was found that the combination of phosphate anions into clusters and the introduction of carboxylate anions into the structure of clusters leads to a change in the packaging of both OPIP and the polyurethanes obtained using them.

полиуретановые иономерынадмолекулярная структураполимерные гелевые электролитыpolyurethane ionomerssupramolecular structurepolymer gel electrolytesReferencesShen H., Wu G., Ma T., Li M., Tian Y., Chen S., Cai S,. Li Z. Lithiophilic interlayer with electrolyte-reservoir and dendrite-buffer for high-performance lithium metal batteries // Nanomaterials. 2025. Vol. 15. P. 710. DOI:10.1021/acsenergylett.9b01987.Shen H., Wu G., Ma T., Li M., Tian Y., Chen S., Cai S,. Li Z. Lithiophilic interlayer with electrolyte-reservoir and dendrite-buffer for high-performance lithium metal batteries // Nanomaterials. 2025. Vol. 15. P. 710. DOI:10.1021/acsenergylett.9b01987.Senthilkumar K.K., Thiruvengadathan R., Raghava R.B.T.S. Recent advancements in Na super ionic conductor-incorporated composite polymer electrolytes for sodium-ion battery application // Electro chem. 2025. Vol. 6. P. 6. DOI:10.3390/electrochem6010006.Senthilkumar K.K., Thiruvengadathan R., Raghava R.B.T.S. Recent advancements in Na super ionic conductor-incorporated composite polymer electrolytes for sodium-ion battery application // Electro chem. 2025. Vol. 6. P. 6. DOI:10.3390/electrochem6010006.Sare H., Dong D. Electrochromic polymers: from electrodeposition to hybrid solid devices // Energies. 2024. Vol. 17. P. 232. DOI:10.3390/en17010232.Sare H., Dong D. Electrochromic polymers: from electrodeposition to hybrid solid devices // Energies. 2024. Vol. 17. P. 232. DOI:10.3390/en17010232.Gao Y., Yan, Z., Gray J. L., He X., Wang D., Chen T., Huang Q., Li Y.C., Wang H., Kim S.H., Mallouk T.E., Wang D. Polymer inorganic solid-electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions // Nat. Mater. 2019. Vol. 18. P. 384–389. DOI: 10.1038/s41563-019-0305-8.Gao Y., Yan, Z., Gray J. L., He X., Wang D., Chen T., Huang Q., Li Y.C., Wang H., Kim S.H., Mallouk T.E., Wang D. Polymer inorganic solid-electrolyte interphase for stable lithium metal batteries under lean electrolyte conditions // Nat. Mater. 2019. Vol. 18. P. 384–389. DOI: 10.1038/s41563-019-0305-8.Chen S., Wen, K., Fan J., Bando Y., Golberg D. Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes // J. Mater. Chem. 2018. Vol. 6. P. 11631–11663. DOI:10.1039/C8TA03358G.Chen S., Wen, K., Fan J., Bando Y., Golberg D. Progress and future prospects of high-voltage and high-safety electrolytes in advanced lithium batteries: from liquid to solid electrolytes // J. Mater. Chem. 2018. Vol. 6. P. 11631–11663. DOI:10.1039/C8TA03358G.Cho Y.-G., Hwang C., Cheong D.S., Kim Y.-S., Song H.-K. Gel/solid polymer electrolytes characterized by in situ gelation or polymerization for electrochemical energy systems // Adv. Mater. 2019. Vol. 31, N20. P. 1804909. DOI: 10.1038/s41563-019-0305-8.Cho Y.-G., Hwang C., Cheong D.S., Kim Y.-S., Song H.-K. Gel/solid polymer electrolytes characterized by in situ gelation or polymerization for electrochemical energy systems // Adv. Mater. 2019. Vol. 31, N20. P. 1804909. DOI: 10.1038/s41563-019-0305-8.Shin I., Nam J., Lee K., Kim E., Kim T.-H. Poly(ethylene glycol) (PEG)-crosslinked poly(vinyl pyridine)-PEG-poly(vinyl pyridine) based triblock copolymers prepared by RAFT polymerization as novel gel polymer electrolytes // Polym. Chem. 2018. Vol. 9. P. 5190–5199. DOI:10.1039/C8PY01097H.Shin I., Nam J., Lee K., Kim E., Kim T.-H. Poly(ethylene glycol) (PEG)-crosslinked poly(vinyl pyridine)-PEG-poly(vinyl pyridine) based triblock copolymers prepared by RAFT polymerization as novel gel polymer electrolytes // Polym. Chem. 2018. Vol. 9. P. 5190–5199. DOI:10.1039/C8PY01097H.Ma Y., Ma J., Chai J., Liu Z., Ding G., Xu G., Liu H., Chen B., Zhou X., Cui G., Chen L. Two players make a formidable combination: in situ generated poly(acrylic anhydride-2-methyl-acrylic acid-2-oxirane-ethyl ester-methyl methacrylate) cross-linking gel polymer electrolyte toward 5 V high-voltage batteries // ACS Appl. Mater. Interfaces. 2017. Vol. 9. P. 41462–41472. DOI:10.1021/acsami.7b11342.Ma Y., Ma J., Chai J., Liu Z., Ding G., Xu G., Liu H., Chen B., Zhou X., Cui G., Chen L. Two players make a formidable combination: in situ generated poly(acrylic anhydride-2-methyl-acrylic acid-2-oxirane-ethyl ester-methyl methacrylate) cross-linking gel polymer electrolyte toward 5 V high-voltage batteries // ACS Appl. Mater. Interfaces. 2017. Vol. 9. P. 41462–41472. DOI:10.1021/acsami.7b11342.Gao L., Li J.X., Sarmad B., Cheng B.W., Kang W.M., Deng N.P. A 3D polyacrylonitrile nanofiber and flexible polydimethylsiloxane macromolecule combined all-solid-state composite electrolyte for efficient lithium metal batteries // Nanoscale. 2020. Vol. 12. P. 14279-14289. DOI:10.1039/d0nr04244g.Gao L., Li J.X., Sarmad B., Cheng B.W., Kang W.M., Deng N.P. A 3D polyacrylonitrile nanofiber and flexible polydimethylsiloxane macromolecule combined all-solid-state composite electrolyte for efficient lithium metal batteries // Nanoscale. 2020. Vol. 12. P. 14279-14289. DOI:10.1039/d0nr04244g.Liang Y.F., Deng S.J., Xia Y., Wang X.L., Xia X.H., Wu J.B., Gu C.D., Tu J.P. A superior composite gel polymer electrolyte of Li7La3Z r2O12 poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) for rechargeable solid-state lithium ion batteries // Mater. Res. Bull. 2018. Vol. 102. P. 412–417. DOI:10.1016/j.materresbull.2018.02.051.Liang Y.F., Deng S.J., Xia Y., Wang X.L., Xia X.H., Wu J.B., Gu C.D., Tu J.P. A superior composite gel polymer electrolyte of Li7La3Z r2O12 poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) for rechargeable solid-state lithium ion batteries // Mater. Res. Bull. 2018. Vol. 102. P. 412–417. DOI:10.1016/j.materresbull.2018.02.051.Lv Z., Tang Y., Dong S., Zhou Q., Cui G. Polyurethane-based polymer electrolytes for lithium Batteries: Advances and perspectives // Chem. Eng. J. 2022. Vol. 430. P. 132659. DOI:10.1039/d4ra06863g.Lv Z., Tang Y., Dong S., Zhou Q., Cui G. Polyurethane-based polymer electrolytes for lithium Batteries: Advances and perspectives // Chem. Eng. J. 2022. Vol. 430. P. 132659. DOI:10.1039/d4ra06863g.Lin Z., Guo X., Yang Y., Tang M., Wei Q., Yu H. Block copolymer electrolyte with adjustable functional units for solid polymer lithium metal battery // J. Energy Chem. 2021. Vol. 52. P. 67–74. DOI:10.1016/j.jechem.2020.04.052.Lin Z., Guo X., Yang Y., Tang M., Wei Q., Yu H. Block copolymer electrolyte with adjustable functional units for solid polymer lithium metal battery // J. Energy Chem. 2021. Vol. 52. P. 67–74. DOI:10.1016/j.jechem.2020.04.052.Gao Y., Wang C., Wang H., Feng C., Pan H., Zhang Z., He J., Wang Q. Polyurethane/LLZTO solid electrolyte with excellent mechanical strength and electrochemical property for advanced lithium metal battery // Chem. Eng. J. 2023. Vol. 474. P. 145446. DOI:10.1016/j.cej.2023.145446.Gao Y., Wang C., Wang H., Feng C., Pan H., Zhang Z., He J., Wang Q. Polyurethane/LLZTO solid electrolyte with excellent mechanical strength and electrochemical property for advanced lithium metal battery // Chem. Eng. J. 2023. Vol. 474. P. 145446. DOI:10.1016/j.cej.2023.145446.Jaumaux P., Liu Q., Zhou D., Xu X., Wang T., Wang Y., Kang F., Li B., Wang G. Deep-eutectic-solvent-based self-healing polymer electrolyte for safe and long-life lithium-metal batteries // Angew. Chem. Int. Ed. 2020. Vol. 59. P. 91349142. DOI:10.1002/anie.202001793.Jaumaux P., Liu Q., Zhou D., Xu X., Wang T., Wang Y., Kang F., Li B., Wang G. Deep-eutectic-solvent-based self-healing polymer electrolyte for safe and long-life lithium-metal batteries // Angew. Chem. Int. Ed. 2020. Vol. 59. P. 91349142. DOI:10.1002/anie.202001793.Wang H., Li X., Zeng Q., Li Z., Liu Y., Guan J., Jiang Y., Chen L., Cao Y., Li R. A novel hyperbranched polyurethane solid electrolyte for room temperature ultra-long cycling lithium-ion batteries // Energy Storage Mater. 2024. Vol. 66. P. 103188. DOI:10.1016/j.ensm.2024.103188.Wang H., Li X., Zeng Q., Li Z., Liu Y., Guan J., Jiang Y., Chen L., Cao Y., Li R. A novel hyperbranched polyurethane solid electrolyte for room temperature ultra-long cycling lithium-ion batteries // Energy Storage Mater. 2024. Vol. 66. P. 103188. DOI:10.1016/j.ensm.2024.103188.Davletbaeva I.M., Nizamov A.A., Yudina A.V., Baymuratova G.R., Yarmolenko O.V., Sazonov O.O., Davletbaev R.S. Gel-polymer electrolytes based on polyurethane ionomers for lithium power sources // RSC Adv. 2021. Vol. 11. P. 21548. DOI:10.1039/D1RA01312BDavletbaeva I.M., Nizamov A.A., Yudina A.V., Baymuratova G.R., Yarmolenko O.V., Sazonov O.O., Davletbaev R.S. Gel-polymer electrolytes based on polyurethane ionomers for lithium power sources // RSC Adv. 2021. Vol. 11. P. 21548. DOI:10.1039/D1RA01312B

The authors declare that there are no conflicts of interest present.