<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">plasticnews</journal-id><journal-title-group><journal-title xml:lang="ru">Пластические массы</journal-title><trans-title-group xml:lang="en"><trans-title>Plasticheskie massy</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">0554-2901</issn><publisher><publisher-name>PLASTMASSY Publishing House (Moscow)</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.35164/0554-2901-2025-05-47-49</article-id><article-id custom-type="elpub" pub-id-type="custom">plasticnews-1181</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Статьи</subject></subj-group></article-categories><title-group><article-title>Исследование процесса отверждения бензоксазина на основе бисфенола А и анилина методом ДСК</article-title><trans-title-group xml:lang="en"><trans-title>Investigation of the curing process of benzoxazine based on bisphenol A and aniline by the DSC method</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шутов</surname><given-names>В. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Shutov</surname><given-names>V. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Москва </p></bio><bio xml:lang="en"><p>Moscow </p></bio><email xlink:type="simple">shutov.v.v@muctr.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Горбунова</surname><given-names>И. Ю.</given-names></name><name name-style="western" xml:lang="en"><surname>Gorbunova</surname><given-names>I. Yu.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Москва </p></bio><bio xml:lang="en"><p>Moscow </p></bio><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Российский химико-технологический университет им. Д.И. Менделеева</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Mendeleev University of Chemical Technology of Russia</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2025</year></pub-date><pub-date pub-type="epub"><day>10</day><month>11</month><year>2025</year></pub-date><volume>0</volume><issue>5</issue><fpage>47</fpage><lpage>49</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Шутов В.В., Горбунова И.Ю., 2025</copyright-statement><copyright-year>2025</copyright-year><copyright-holder xml:lang="ru">Шутов В.В., Горбунова И.Ю.</copyright-holder><copyright-holder xml:lang="en">Shutov V.V., Gorbunova I.Y.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://www.plastics-news.ru/jour/article/view/1181">https://www.plastics-news.ru/jour/article/view/1181</self-uri><abstract><p>В работе исследован процесс отверждения бензоксазина на основе бисфенола А и анилина методом дифференциальной сканирующей калориметрии. При помощи подхода, предложенного Вязовкиным, в рабочей среде MATLAB® были рассчитаны зависимости эффективной энергии активации (Еα) от степени отверждения (α). Форма зависимостей Еα от α позволила выявить сложный характер процесса отверждения.</p></abstract><trans-abstract xml:lang="en"><p>The curing process of benzoxazine based on bisphenol A and aniline was studied using differential scanning calorimetry. Using the approach proposed by Vyazovkin, the dependences of the effective activation energy (Еα) on the degree of curing (α) were calculated in the MATLAB® working environment. The shape of the dependences of Еα on α revealed the complex character of the curing process.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>бензоксазины</kwd><kwd>кинетика отверждения</kwd><kwd>метод Вязовкина</kwd><kwd>безмодельная кинетика</kwd></kwd-group><kwd-group xml:lang="en"><kwd>benzoxazines</kwd><kwd>curing kinetics</kwd><kwd>Vyazovkin approach</kwd><kwd>model-free kinetics</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Ishida H. Overview and historical background of polybenzoxazine research / Handbook of Benzoxazine Resins. 2011. P. 3–81. DOI: 10.1016/B978-0-444-53790-4.00046-1.</mixed-citation><mixed-citation xml:lang="en">Ishida H. Overview and historical background of polybenzoxazine research / Handbook of Benzoxazine Resins. 2011. P. 3–81. DOI: 10.1016/B978-0-444-53790-4.00046-1.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Vyazovkin S., Achilias D., Fernandez-Francos X., Galukhin A., Sbirrazzuoli N. ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics // Thermochimica Acta. 2022. Vol. 714. P. 179243. DOI:10.1016/j.tca.2022.179243.</mixed-citation><mixed-citation xml:lang="en">Vyazovkin S., Achilias D., Fernandez-Francos X., Galukhin A., Sbirrazzuoli N. ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics // Thermochimica Acta. 2022. Vol. 714. P. 179243. DOI:10.1016/j.tca.2022.179243.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Ning X., Ishida H. Phenolic materials via ring-opening polymerization: Synthesis and characterization of bisphenol-A based benzoxazines and their polymers // Journal of Polymer Science Part A: Polymer Chemistry. 1994. Vol. 32, N6. P. 1121–1129. DOI: 10.1002/pola.1994.080320614.</mixed-citation><mixed-citation xml:lang="en">Ning X., Ishida H. Phenolic materials via ring-opening polymerization: Synthesis and characterization of bisphenol-A based benzoxazines and their polymers // Journal of Polymer Science Part A: Polymer Chemistry. 1994. Vol. 32, N6. P. 1121–1129. DOI: 10.1002/pola.1994.080320614.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Wang M.W., Jeng R.J., Lin C.H. Study on the Ring-Opening Polymerization of Benzoxazine through Multisubstituted Polybenzoxazine Precursors // Macromolecules. 2015. Vol. 48, N3. P. 530-535. DOI: 10.1021/ma502336j.</mixed-citation><mixed-citation xml:lang="en">Wang M.W., Jeng R.J., Lin C.H. Study on the Ring-Opening Polymerization of Benzoxazine through Multisubstituted Polybenzoxazine Precursors // Macromolecules. 2015. Vol. 48, N3. P. 530-535. DOI: 10.1021/ma502336j.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Vyazovkin S. Modification of the integral isoconversional method to account for variation in the activation energy // Journal of Computational Chemistry. 2001. Vol. 22, N2. P. 178–183. DOI 10.1002/1096-987X(20010130)22:2&lt;178::AID-JCC5&gt;3.0.CO;2-CO;2-%23.</mixed-citation><mixed-citation xml:lang="en">Vyazovkin S. Modification of the integral isoconversional method to account for variation in the activation energy // Journal of Computational Chemistry. 2001. Vol. 22, N2. P. 178–183. DOI 10.1002/1096-987X(20010130)22:2&lt;178::AID-JCC5&gt;3.0.CO;2-CO;2-%23.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Vyazovkin S. Evaluation of activation energy of thermally stimulated solid-state reactions under arbitrary variation of temperature // Journal of Computational Chemistry. 1997. Vol. 18, N3. P. 393–402. DOI 10.1002/(SICI)1096-987X(199702)18:3&lt;393::AIDJCC9&gt;3.0.CO;2-P.</mixed-citation><mixed-citation xml:lang="en">Vyazovkin S. Evaluation of activation energy of thermally stimulated solid-state reactions under arbitrary variation of temperature // Journal of Computational Chemistry. 1997. Vol. 18, N3. P. 393–402. DOI 10.1002/(SICI)1096-987X(199702)18:3&lt;393::AIDJCC9&gt;3.0.CO;2-P.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Ishida H., Rodriguez Y. Curing kinetics of a new benzoxazine-based phenolic resin by differential scanning calorimetry // Polymer. 1995. Vol. 36, N16. P. 3151–3158. DOI: 10.1016/0032-3861(95)97878-J.</mixed-citation><mixed-citation xml:lang="en">Ishida H., Rodriguez Y. Curing kinetics of a new benzoxazine-based phenolic resin by differential scanning calorimetry // Polymer. 1995. Vol. 36, N16. P. 3151–3158. DOI: 10.1016/0032-3861(95)97878-J.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Hassan W. A., Liu J., Howlin B. J., Ishida H., Hamerton I. Examining the influence of bisphenol A on the polymerisation and network properties of an aromatic benzoxazine // Polymer. 2016. Vol. 88. P. 52–62. DOI: 10.1016/j.polymer.2016.01.041.</mixed-citation><mixed-citation xml:lang="en">Hassan W. A., Liu J., Howlin B. J., Ishida H., Hamerton I. Examining the influence of bisphenol A on the polymerisation and network properties of an aromatic benzoxazine // Polymer. 2016. Vol. 88. P. 52–62. DOI: 10.1016/j.polymer.2016.01.041.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Sun J., Wei W., Xu Y., Qu J., Liu X et al. A curing system of benzoxazine with amine: reactivity, reaction mechanism and material properties // RSC Advances. – 2015. Vol. 5, N25. Р. 19048–19057. DOI: 10.1039/C4RA16582A.</mixed-citation><mixed-citation xml:lang="en">Sun J., Wei W., Xu Y., Qu J., Liu X et al. A curing system of benzoxazine with amine: reactivity, reaction mechanism and material properties // RSC Advances. – 2015. Vol. 5, N25. Р. 19048–19057. DOI: 10.1039/C4RA16582A.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Hamerton I., McNamara L. T., Howlin B. J., Smith P.A., Cross P. et al. Examining the Initiation of the Polymerization Mechanism and Network Development in Aromatic Polybenzoxazines // Macromolecules. 2013. Vol. 46, N13. P. 5117–5132. DOI: 10.1021/ma401014h.</mixed-citation><mixed-citation xml:lang="en">Hamerton I., McNamara L. T., Howlin B. J., Smith P.A., Cross P. et al. Examining the Initiation of the Polymerization Mechanism and Network Development in Aromatic Polybenzoxazines // Macromolecules. 2013. Vol. 46, N13. P. 5117–5132. DOI: 10.1021/ma401014h.</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Liu C., Shen D., Sebastián R. M., Marquet J., Schönfeld R. Mechanistic Studies on Ring-Opening Polymerization of Benzoxazines: A Mechanistically Based Catalyst Design // Macromolecules. 2011. Vol. 44. N12. – P. 4616–4622. DOI: 10.1021/ma2007893.</mixed-citation><mixed-citation xml:lang="en">Liu C., Shen D., Sebastián R. M., Marquet J., Schönfeld R. Mechanistic Studies on Ring-Opening Polymerization of Benzoxazines: A Mechanistically Based Catalyst Design // Macromolecules. 2011. Vol. 44. N12. – P. 4616–4622. DOI: 10.1021/ma2007893.</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Chutayothin P., Ishida H. Cationic Ring-Opening Polymerization of 1,3-Benzoxazines: Mechanistic Study Using Model Compounds // Macromolecules. 2010. Vol. 43. N10. P. 4562–4572. DOI: 10.1021/ma901743h.</mixed-citation><mixed-citation xml:lang="en">Chutayothin P., Ishida H. Cationic Ring-Opening Polymerization of 1,3-Benzoxazines: Mechanistic Study Using Model Compounds // Macromolecules. 2010. Vol. 43. N10. P. 4562–4572. DOI: 10.1021/ma901743h.</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Furuncuoğlu Özaltın T., Catak S., Kiskan B., Yagci Y., Aviyente V. Rationalizing the regioselectivity of cationic ring-opening polymerization of benzoxazines // European Polymer Journal. 2018. Vol. 105. P. 61–67. DOI: 10.1016/j.eurpolymj.2018.05.024.</mixed-citation><mixed-citation xml:lang="en">Furuncuoğlu Özaltın T., Catak S., Kiskan B., Yagci Y., Aviyente V. Rationalizing the regioselectivity of cationic ring-opening polymerization of benzoxazines // European Polymer Journal. 2018. Vol. 105. P. 61–67. DOI: 10.1016/j.eurpolymj.2018.05.024.</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Fan M.J., Zhou Y., Luan Y.H., Zang Q., Zhang D.X. et. al. Non-Isothermal Curing Kinetics of a Modified Benzoxazine Resin System Suitable for Hot-Melt Prepreg Preparation // Solid State Phenomena. 2017. Vol. 266. P. 128–134. DOI: 10.4028/www.scientific.net/SSP.266.128.</mixed-citation><mixed-citation xml:lang="en">Fan M.J., Zhou Y., Luan Y.H., Zang Q., Zhang D.X. et. al. Non-Isothermal Curing Kinetics of a Modified Benzoxazine Resin System Suitable for Hot-Melt Prepreg Preparation // Solid State Phenomena. 2017. Vol. 266. P. 128–134. DOI: 10.4028/www.scientific.net/SSP.266.128.</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Ručigaj A., Gradišar Š., Krajnc M. Kinetic investigation of a complex curing of the guaiacol bio-based benzoxazine system // e-Polymers. 2016. Vol. 16. N3. P. 199–206. DOI: 10.1515/epoly-2015-0250.</mixed-citation><mixed-citation xml:lang="en">Ručigaj A., Gradišar Š., Krajnc M. Kinetic investigation of a complex curing of the guaiacol bio-based benzoxazine system // e-Polymers. 2016. Vol. 16. N3. P. 199–206. DOI: 10.1515/epoly-2015-0250.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Barjasteh E., Gouni S., Sutanto C., Narongdej P. Bisphenol-A benzoxazine and cycloaliphatic epoxy copolymer for composite processing by resin infusion // Journal of Composite Materials. 2019. Vol.53, N13. P. 1777–1790. DOI: 10.1177/0021998318810841.</mixed-citation><mixed-citation xml:lang="en">Barjasteh E., Gouni S., Sutanto C., Narongdej P. Bisphenol-A benzoxazine and cycloaliphatic epoxy copolymer for composite processing by resin infusion // Journal of Composite Materials. 2019. Vol.53, N13. P. 1777–1790. DOI: 10.1177/0021998318810841.</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Bai Y., Yang P., Zhang S., Li Y., Gu Y. Curing kinetics of phenolphthalein–aniline-based benzoxazine investigated by non-isothermal differential scanning calorimetry // Journal of Thermal Analysis and Calorimetry. 2015. Vol. 120. N3. P. 1755–1764. DOI: 10.1007/s10973-015-4544-x.</mixed-citation><mixed-citation xml:lang="en">Bai Y., Yang P., Zhang S., Li Y., Gu Y. Curing kinetics of phenolphthalein–aniline-based benzoxazine investigated by non-isothermal differential scanning calorimetry // Journal of Thermal Analysis and Calorimetry. 2015. Vol. 120. N3. P. 1755–1764. DOI: 10.1007/s10973-015-4544-x.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
